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Tribological Properties of TiN/Ag Nanocomposite Coatings

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Abstract

Morphology, structure, and tribological behavior of magnetron co-sputtered TiN/Ag nanocomposite coatings deposited at 150 °C with an Ag content in the range of 7–45 at.% were characterized. The coatings show a columnar structure with embedded Ag crystallites of 3–50 nm in diameter, where the columns are characterized by a layered structure with Ag-poor and Ag-rich layers. These layers originate from sample rotation during deposition, where the layer thickness increases with increasing Ag content. These Ag layers become continuous over a critical Ag content. At room temperature the friction coefficient is determined by the film structure, whereas friction and wear at high temperature depend on segregation of Ag to the surface.

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References

  1. Polcar, T., Kubart, T., Novak, R., Kopecky, L., Siroky, P.: Comparison of tribological behavior of TiN, TiCN and CrN at elevated temperatures. Surf. Coat. Technol. 193, 192–199 (2005)

    Article  CAS  Google Scholar 

  2. Derflinger, V., Brändle, H., Zimmermann, H.: New hard/lubricant coating for dry machining. Surf. Coat. Technol. 113, 286–292 (1999)

    Article  CAS  Google Scholar 

  3. Voevodin, A.A., O’Neill, J.P., Zabinski, J.S.: Nanocomposite tribological coatings for aerospace applications. Surf. Coat. Technol. 116–119, 36–45 (1999)

    Article  Google Scholar 

  4. Carrera, S., Salas, O., Moore, J.J., Woolverton, A., Sutter, E.: Performance of CrN/MoS2 (Ti) coatings for high wear low friction applications. Surf. Coat. Technol. 167, 25–32 (2003)

    Article  CAS  Google Scholar 

  5. Hirvonen, J.-P., Koskinen, J., Jervis, J.R., Nastasi, M.: Present progress in the development of low friction coatings. Surf. Coat. Technol. 80, 139–150 (1996)

    Article  CAS  Google Scholar 

  6. Ma, K.J., Chao, C.L., Liu, D.S., Chen, Y.T., Shieh, M.B.: Friction and wear behaviour of TiN/Au, TiN/MoS2 and TiN/TiCN/a-C:H coatings. J. Mater. Proc. Technol. 127, 182–186 (2002)

    Article  CAS  Google Scholar 

  7. Fateh, N., Fontalvo, G.A., Gassner, G., Mitterer, C.: Influence of high-temperature oxide formation on the tribological behaviour of TiN and VN coatings. Wear 262, 1152–1158 (2007)

    Article  CAS  Google Scholar 

  8. Gassner, G., Mayrhofer, P.H., Kutschej, K., Mitterer, C., Kathrein, M.: A new low friction concept for high temperatures: lubricious oxide formation on sputtered VN coatings. Tribol. Lett. 17, 751–756 (2004)

    Article  CAS  Google Scholar 

  9. Kutschej, K., Mayrhofer, P.H., Kathrein, M., Polcik, P., Mitterer, C.: A new low-friction concept for Ti1-xAlxN base coatings in high-temperature applications. Surf. Coat. Technol. 188–189, 358–363 (2004)

    Article  Google Scholar 

  10. Voevodin, A.A., Hu, J.J., Fitz, T.A., Zabinski, J.S.: Tribological properties of adaptive nanocomposite coatings made of yttria stabilized zirconia and gold. Surf. Coat. Technol. 146–147, 351–356 (2001)

    Article  Google Scholar 

  11. Muratore, C., Voevodin, A.A., Hu, J.J., Zabinski, J.S.: Tribology of adaptive nanocomposite yttria-stabilized zirconia coatings containing silver and molybdenum from 25 to 700°C. Wear 261, 797–805 (2006)

    Article  CAS  Google Scholar 

  12. Muratore, C., Hu, J.J., Voevodin, A.A.: Adaptive nanocomposite coatings with a titanium nitride diffusion barrier mask for high-temperature tribological applications. Thin Solid Films 515, 3638–3643 (2007)

    Article  CAS  Google Scholar 

  13. Hu, J.J., Muratore, C., Voevodin, A.A.: Silver diffusion and high-temperature lubrication mechanisms of YSZ-Ag-Mo based nanocomposite coatings. Compos. Sci. Technol. 67, 336–347 (2007)

    Article  CAS  Google Scholar 

  14. Mulligan, C.P., Gall, D.: CrN-Ag self-lubricating hard coatings. Surf. Coat. Technol. 200, 1495–1500 (2005)

    Article  CAS  Google Scholar 

  15. Kutschej, K., Mitterer, C., Mulligan, C.P., Gall, D.: High-temperature tribological behavior of CrN-Ag self-lubricating coatings. Adv. Eng. Mater. 11, 1125–1129 (2006)

    Article  Google Scholar 

  16. Abourayak, K., Fayeulle, S., Vincent, L., Ribeiro, C., Cavaleiro, A., Vieira, M.T.: Tribological behaviour at elevated temperatures of thin physical vapour deposited coatings. Surf. Coat. Technol. 80, 171–175 (1996)

    Article  CAS  Google Scholar 

  17. Endrino, J.L., Nainaparampil, J.J., Krzanowski, J.E.: Magnetron sputter deposition of WC-Ag and TiC-Ag coatings and their frictional properties in vacuum environments. Scr. Mater. 47, 613–618 (2002)

    Article  CAS  Google Scholar 

  18. Jirout, M., Musil, J.: Effect of addition of Cu into ZrOx film on its properties. Surf. Coat. Technol. 200, 6792–6800 (2006)

    Article  CAS  Google Scholar 

  19. Musil, J., Jirout, M.: Toughness of hard nanostructured ceramic thin films. Surf. Coat. Technol. 201, 5148–5152 (2007)

    Article  CAS  Google Scholar 

  20. Zhang, S., Sun, D., Fu, Y., Du, H.: Toughening of hard nanostructural thin films: a critical review. Surf. Coat. Technol. 198, 2–8 (2005)

    Article  CAS  Google Scholar 

  21. Zhang, S., Sun, D., Fu, Y., Pei, Y.T., De Hosson, J.Th.M.: Ni-toughened nc-TiN/a-SiNx nanocomposite thin films. Surf. Coat. Technol. 200, 1530–1534 (2005)

    Article  CAS  Google Scholar 

  22. Voevodin, A.A., Zabinski, J.S.: Supertough wear-resistant coatings with “chameleon” surface adaptation. Thin Solid Films 370, 223–231 (2000)

    Article  CAS  Google Scholar 

  23. Köstenbauer, H., Fontalvo, G.A., Mitterer, C., Hlawacek, G., Teichert, C., Keckes, J.: Structure, stresses and stress relaxation of TiN/Ag nanocomposite films. J. Nanosci. Nanotechnol. (accepted)

  24. Teichert, C.: Self-organization of nanostructures in semiconductor heteroepitaxy. Phys. Rep. 365, 335–432 (2002)

    Article  CAS  Google Scholar 

  25. Warren, B.E.: X-ray Diffraction. Dover Publications, New York (1990)

    Google Scholar 

  26. Delhez, R., de Keijser, Th.H., Mittemeijer, E.J.: Determination of crystallite size and lattice distortions through X-ray diffraction line profile analysis – recipes, methods and comments. Fresenius Z Anal. Chem. 312, 1 (1982)

    Article  CAS  Google Scholar 

  27. Petrov, I., Barna, P.B., Hultman, L., Greene, J.E.: Microstructural evolution during film growth. J. Vac. Sci. Technol. A 21, 117–128 (2003)

    Article  Google Scholar 

  28. Mayrhofer, P.H., Hörling, A., Karlsson, L., Sjölen, J., Larsson, T., Mitterer, C., Hultman, L.: Self-organized nanostructures in the Ti-Al-N system. Appl. Phys. Lett. 83, 2051–2094 (2003)

    Article  Google Scholar 

  29. Fontalvo, G.A., Humer, R., Mitterer, C., Sammt, K., Schemmel, I.: Microstructural aspects determining the adhesive wear of tool steels. Wear 260, 1028–1034 (2006)

    Article  CAS  Google Scholar 

  30. Berthier, Y., Godet, M., Brendle, M.: Velocity accommodation in friction. Tribol. Trans. 32, 490–496 (1989)

    Article  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Austrian NANO Initiative via a grant from the Austrian Science Fund FWF (project N401-NAN). The authors would like to thank Prof. C. Teichert, Dr. G. Hlawacek, and T. Klünsner for their support with AFM measurements.

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Correspondence to Harald Köstenbauer.

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Köstenbauer, H., Fontalvo, G.A., Mitterer, C. et al. Tribological Properties of TiN/Ag Nanocomposite Coatings. Tribol Lett 30, 53–60 (2008). https://doi.org/10.1007/s11249-008-9312-7

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  • DOI: https://doi.org/10.1007/s11249-008-9312-7

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