Abstract
Tribological characteristics of two imidazolium-based room temperature ionic liquids (RTILs), 1-hexyl-3-methylimidazolium tetrafluoroborate, and 1-hexyl-3-methylimidazolium hexafluorophosphate were investigated under high vacuum conditions. Viscosity–temperature characteristics and thermogravimetric characteristics of these compounds were also investigated. Imidazolium-based RTILs have relatively good viscosity–temperature characteristics that are comparable to those of multiply-alkylated cyclopentane (MAC). Thermogravimetric results showed that ionic liquids have high thermal stability and low vapor pressure. Ionic liquids showed low friction and low wear rate under high vacuum conditions, and high load-carrying capacity was observed.
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Jones, W.R. Jr., Jansen, M.J.: Space Tribology. NASA/TM-2000-209924 (2000)
Freeman, M.T.: Spacecraft on-orbit deployment anomalies. IEEE Aero. El. Sys. Mag. 8, 3–15 (1993)
Takano, A.: Tribology-related space mechanism anomalies and the newly constructed high-vacuum mechanism test facilities in NASDA. Tribol. Int. 32, 661–671 (1999)
Marchetti, M., Jones, W.R. Jr., Street, K.W., Pepper, S.V., Jansen, M.J.: Preliminary Evaluation of Greases for Space Mechanisms Using a Vacuum Spiral Orbit Tribometer. NASA/TM-2001-211157 (2001)
Hagiwara, R., Ito, Y.: Room temperature ionic liquids of alkylimidazalium cations and fluoroanions. J. Fluorine. Chem. 105, 221–227 (2000)
Welton, T.: Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem. Rev. 99, 2071–2083 (1999)
Wilkes, J.S.: A short history of ionic liquids–from molten salts to neoteric solvents. Green. Chem. 4, 73–80 (2002)
Ye, C., Liu, W., Chen, Y., Yu, L.: Room-temperature ionic liquids: a novel versatile lubricant. Chem. Commun., 2244–2245 (2001)
Liu, W., Ye, C., Chen, Y., Ou, Z., Sun, D.C.: Tribological behavior of sialon ceramics sliding against steel lubricated by fluorine-containing oils. Tribol. Int. 35, 503–509 (2002)
Reich, R.A., Stewart, P.A., Bohaychick, J. Urbanski, J.A.: Base oil properties of ionic liquids. Lubr. Eng. 7, 16–21 (2003)
Wang, H., Lu, Q., Ye, C., Liu, W., Cui, Z.: Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact. Wear 256, 44–48 (2004)
Lu, Q.M., Wang, H.Z., Ye, C.F., Liu, W.M., Xue, Q.J.: Room-temperature ionic liquid 1-ethyl-3-hexylimidazolium-bis(trifluoromethylsulfonyl)imide as lubricant for steel-steel contact. Tribol. Int. 37, 547–552 (2004)
Mu, Z., Zhou, F., Zhang, S., Liang, Y., Liu, W.: Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact. Tribol. Int. 38, 725–731 (2005)
Yu, G., Zhou, F., Liu, W., Liang, Y., Yan, S.: Preparation of functional ionic liquids and tribological investigation of their ultra-thin films. Wear 260, 1076–1080 (2006)
Yu, B., Zhou, F., Mu, Z., Liang, Y., Liu, W.: Tribological properties of ultra-thin ionic liquid films on single-crystal silicon wafers with functionalized surfaces. Tribol. Int. 39, 879–887 (2006)
Jiménez, A.E., Bermúdez, M.D., Iglesias, P., Carrión, F.J., Martínez-Nicolás, G.: 1-N-alkyl-3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel-aluminium contacts. Wear 260, 766–782 (2006)
Jiménez, A.E., Bermúdez, M.D., Carrión, F.J., Martínez-Nicolás, G.: Room temperature ionic liquids as lubricant additives in steel-aluminium contacts: Influence of sliding velocity, normal load and temperature. Wear 261, 347–359 (2006)
Cull, S.G., Holbrey, J.D., Vargas-Mora, V., Seddon, K.R., Lye, G.J.: Room-temperature ionic liquids as replacements for organic solvents in multiphase bioprocess operations. Biotechnol. Bioeng. 69, 227–233 (2000)
Kubisa, P.: Application of ionic liquids as solvents for polymerization processes. Progr. Poly. Sci. 29, 3–12 (2004)
Yang, Z., Pan, W.: Ionic liquids: Green solvents for nonaqueous biocatalysis. Enzyme Microb. Technol. 37, 19–28 (2005)
Berthod, A., Ruiz-Angel, M.J., Huguet, S.: Nonmolecular solvents in separation methods: Dual nature of room temperature ionic liquids. Anal. Chem. 77, 4071–4080 (2005)
Zhao, H., Xia, S., Ma, P.: Use of ionic liquids as ‘green’ solvents for extractions. J. Chem. Technol. Biotechnol. 80, 1089–1096 (2005)
Dietz, M.L.: Ionic liquids as extraction solvents: Where do we stand? Separ. Sci. Technol. 41, 2047–2063 (2006)
Heitzman, H., Young, B.A., Rausch, D.J., Rickert, P., Stepinski, D.C., Dietz, M.L.: Fluorous ionic liquids as solvents for the liquid-liquid extraction of metal ions by macrocyclic polyethers. Talanta 69, 527–531 (2006)
Moens, L., Blake, D.M., Rudnicki, D.L., Hale, M.J.: Advanced thermal storage fluids for solar parabolic trough systems. Trans ASME J. Solar Energy Eng. 125, 112–116 (2003)
Xu, J.J., Ye, H., Huang, J.: Novel zinc ion conducting polymer gel electrolytes based on ionic liquids. Electrochem. Commun. 7, 1309–1317 (2005)
Balducci, A., Soavi, F., Mastragostino, M.: The use of ionic liquids as solvent-free green electrolytes for hybrid supercapacitors. Appl. Phys. A Mater. Sci. Process 82, 627–632 (2006)
Galinski, M., Lewandowski, A., Stepniak, I.: Ionic liquids as electrolytes. Electrochimica Acta 51, 5567–5580 (2006)
Lee, J.S., Quan, N.D., Hwang, J.M., Bae, J.Y., Kim, H., Cho, B.W., Kim, H.S., Lee, H.: Ionic liquids containing an ester group as potential electrolytes. Electrochem. Commun. 8, 460–464 (2006)
Jiménez, A.E., Bermúdez, M.D.: Ionic liquids as lubricants for steel–aluminum contacts at low and elevated temperatures. Tribol. Lett. 26, 53–60 (2007)
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Phillips, B.S., John, G., Zabinski, J.S.: Surface chemistry of fluorine containing ionic liquids on steel substrates at elevated temperature using Mössbauer spectroscopy. Tribol. Lett. 26, 85–91 (2007)
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Suzuki, A., Shinka, Y. & Masuko, M. Tribological Characteristics of Imidazolium-based Room Temperature Ionic Liquids Under High Vacuum. Tribol Lett 27, 307–313 (2007). https://doi.org/10.1007/s11249-007-9235-8
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DOI: https://doi.org/10.1007/s11249-007-9235-8