Skip to main content
Log in

Temperature and acid droplet size effects in acid neutralization of marine cylinder lubricants

  • Published:
Tribology Letters Aims and scope Submit manuscript

Abstract

Temperature and acid droplet size effects on the rate of acid neutralization by Marine Cylinder Lubricants were investigated by using a heating-capillary video microscopy. The neutralization experiments were performed inside a ∼200-μm capillary micro-reactor and the progress of reaction was recorded in real time. Increasing temperature dramatically impacted on the neutralization rate. While the effect of acid droplet size was negligible initially, it might affect the rate as well when a droplet got smaller than a certain level.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1.
Figure 2.
Figure 3.

Similar content being viewed by others

References

  1. Hosonuma K., Tamura K. (1984) Sekiyu Gakkaishi 27(2):108

    CAS  Google Scholar 

  2. J.-P. Roman, New method of measurement in thin film of the neutralization ability of marine lubricants for low-speed and medium-speed diesel engines, Proc. of the 22nd CIMAC Internal. Congress on Combustion Engines, Copenhagen, DK (1998) CIMAC Technical papers & Recommendations

  3. Hone D.C., Robinson B.H., Steytler D.C., Glyde R.W., Galsworthy J.R. (2000) Langmuir 16(2):340

    Article  CAS  Google Scholar 

  4. Wu R.C., Papadopoulos K.D. Campbell C.B. (2000) AIChE. J. 46(7):1471

    Article  CAS  Google Scholar 

  5. Wu R.C., Campbell C.B., Papadopoulos K.D. (2000) Ind. Eng. Chem. Res. 39(10):3926

    Article  CAS  Google Scholar 

  6. Fu J., Lu Y., Campbell C.B., Papadopoulos K.D. (2005) Optical Microscopy inside a Heating Capillary. Ind. Eng. Chem. Res. 44(5):1199

    Article  CAS  Google Scholar 

  7. Stott F.H., Macdonald A.G. (1988) Wear 122(3):343

    Article  CAS  Google Scholar 

  8. ASTM D2896-05. Standard Test Method for Base Number of Petroleum Products by Potentiometric Perchloric Acid Titration; ASTM International

  9. Lemaire B., Bothorel P. (1980) Macromolecules 13(2):311

    Article  CAS  Google Scholar 

  10. J. Fu, Y. Lu, C.B. Campbell and K.D. Papadopoulos, Ind. Eng. Chem. Res. (2006) in press.

  11. Wu R.C., Papadopoulos K.D., Campbell C.B. (1999) AIChE. J. 45(9):2011

    Article  CAS  Google Scholar 

  12. Krapivsky P.L., Ben-Naim E (1994) J. Chem. Phys. 100(9):6778

    Article  CAS  Google Scholar 

  13. Wackenhut M. Herrmann H. (2003) Phy. Rev. E: Stat. Nonlin.Soft Matter Phys. 68(4–1):041303/1

    Google Scholar 

  14. Galsworthy J., Hammond S., Hone D. (2000) Curr. Opin. Colloid Interface Sci. 5(5–6):274

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This research was funded by LEQSF of the Louisiana Board of Regents under its ITRS program, Chevron Oronite Company LLC, and Tulane Institute for Macromolecular Engineering and Science (TIMES).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kyriakos D. Papadopoulos.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fu, J., Lu, Y., Campbell, C.B. et al. Temperature and acid droplet size effects in acid neutralization of marine cylinder lubricants. Tribol Lett 22, 221–225 (2006). https://doi.org/10.1007/s11249-006-9082-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11249-006-9082-z

Keywords

Navigation