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The Features of the CCVD of Trichloroethylene Over Microdispersed Ni and Ni–Mo Catalysts

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Abstract

Self-organizing catalytic systems are promising for synthesis of carbon nanomaterials via catalytic chemical vapor deposition. The precursors of catalysts, 100Ni and 96Ni–4Mo, were synthesized by reductive thermolysis at 800 °C and tested in the H2-assisted catalytic pyrolysis of C2HCl3 to produce carbon nanofibers. The reaction temperature was varied in a range of 475–675 °C. The kinetics of carbon accumulation over the prepared catalysts was studied to reveal the effect of Mo on the catalytic performance of nickel. It was shown that the process is characterized by the presence of induction period, and the addition of molybdenum to nickel leads to a shortening of this period in ~ 70% along with an increase in the C2HCl3 decomposition rate and boosting the carbon yield. The maximum yield of the carbon nanomaterial obtained after 2 h of the C2HCl3 decomposition over 96Ni–4Mo alloy at 600 °C was as high as 89 g/gcat. The presence of Mo in the catalyst’s composition also leads to a decrease in activation energy value from 79 to 55 kJ/mol. The longevity tests performed at 600 °C for 7 h showed that the bimetallic 96Ni–4Mo alloy provides productivity of 259 g/gcat, which is 2.2 times higher than for the monometallic 100Ni catalyst. According to transmission and scanning electron microscopies, the obtained carbon nanomaterial is predominantly represented by long filaments attached to submicron-sized catalytic particles. The carbon nanofibers are characterized by a defective and non-uniform segmented secondary structure and possess high specific surface area (up to 385 m2/g).

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Acknowledgements

Analysis of the physicochemical properties of the samples was performed using the equipment of the “National Center for Catalyst Research”. The authors are grateful to AN Serkova and MN Volochaev for their help in the electron microscopy studies, and to AB Ayupov for the low-temperature nitrogen adsorption/desorption analysis.

Funding

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (project Grant No. AAAA-A21-121011390054-1). The synthesis and X-ray diffraction analysis of the starting materials were supported by the Russian Science Foundation (project Grant No. 21-13-00414).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, pr. Ac. Lavrentieva 5, Novosibirsk, 630090, Russia

    Arina R. Potylitsyna, Yury I. Bauman, Ilya V. Mishakov & Aleksey A. Vedyagin

  2. Novosibirsk State University, str. Pirogova 2, Novosibirsk, 630090, Russia

    Arina R. Potylitsyna, Pavel E. Plyusnin & Yury V. Shubin

  3. Nikolaev Institute of Inorganic Chemistry, Ac. Lavrentieva 3, Novosibirsk, 630090, Russia

    Pavel E. Plyusnin & Yury V. Shubin

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  1. Arina R. Potylitsyna
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Correspondence to Arina R. Potylitsyna.

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Potylitsyna, A.R., Bauman, Y.I., Mishakov, I.V. et al. The Features of the CCVD of Trichloroethylene Over Microdispersed Ni and Ni–Mo Catalysts. Top Catal 66, 326–337 (2023). https://doi.org/10.1007/s11244-022-01698-z

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