Topics in Catalysis

, Volume 61, Issue 20, pp 2142–2151 | Cite as

The Effect of Polarization and Reaction Mixture on the Rh/YSZ Oxidation State During Ethylene Oxidation Studied by Near Ambient Pressure XPS

  • A. Katsaounis
  • D. Teschner
  • S. ZafeiratosEmail author
Original Article


In this study, near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) is applied to investigate an electrochemical cell consisting of a rhodium thin film catalyst supported on an yttria-stabilized zirconia (YSZ) solid electrolyte under various ethylene-oxygen reaction mixtures. The aim of the study is twofold: first to show how the surface oxidation state of the Rh catalyst is correlated with the reactants feed composition and the temperature, and second, to reveal the effect of the anodic polarization on the stability of Rh oxides and the implications on the electrochemical promotion of catalysis. It is clearly shown that even under reducing conditions part of the Rh electrode remains oxidized at temperatures up to 250 °C. Reduction of the oxide can take place by increasing the temperature under C2H4 excess, something which is not happening under oxidizing reaction mixtures. Moreover, anodic polarization, i.e. oxygen ion supply to the surface, facilitates reduction of oxidized Rh electrodes over a broad range of ethylene–oxygen reaction mixtures. Remarkably, under mildly reducing conditions a stable ultrathin Rh surface oxide film forms over metallic Rh. This surface Rh oxide film (RhOx) is associated to higher cell currents, counterintuitive to the case of bulk Rh oxides (Rh2O3).


Electrochemical promotion of catalysis (EPOC) Near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) Rh oxide Ethylene oxidation 



We thank AC department of FHI and in particular M. Hävecker and A. Knop-Gericke for the opportunity to use the ISISS beamline and HZB for the allocation of synchrotron radiation beamtime. We acknowledge the support of Dr. T. Dintzer for the SEM images and Dr. Y.T. Law during the beamtime measurements.


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemical EngineeringUniversity of PatrasPatrasGreece
  2. 2.Fritz-Haber-Institut der MPGBerlinGermany
  3. 3.Max Planck Institute for Chemical Energy ConversionMülheim an der RuhrGermany
  4. 4.Institut de Chimie et Procédés pour l’Energiel’Environnement et la Santé (ICPEES), ECPM, UMR 7515 CNRS-Université de StrasbourgStrasbourg Cedex 02France

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