Abstract
Efficacy of a new approach for the synthesis of graphene oxide (GO) nanosheets that has been recently reported (Ogino et al. in Chem Mater 26:3334–3339, 2014) was investigated further using graphite oxides with various degrees of oxidation and average particle sizes. The approach consists of rapid freeze–thaw cycles of water containing graphite oxide, which enables the efficient exfoliation of graphite oxide layers with the minimal fragmentation of GO sheets. The method is effective for the exfoliation of graphite oxides with C/O atomic ratios ≤2.6 as shown by experiments with various degrees of oxidation of graphite oxides. When this method was tested for large particle-size graphite oxide that had been prepared from graphite with the average particle size of 60 μm, it formed approximately tenfold larger GO sheets than those prepared using sonication. Exfoliation experiments conducted at different freezing rates of water demonstrate that a faster freezing rate of water yielded a higher concentration of a dispersed GO solution. Thus, the results support the hypothesis that rapid phase change enables efficient layer exfoliation.
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Tsapatsis M (2014) AIChE J 60(7):2374–2381
Díaz U, Corma A (2014) Dalton Trans 43(27):10292–10316
Roth WJ, Nachtigall P, Morris RE, Čejka J (2014) Chem Rev 114(9):4807–4837
Takagaki A, Sugisawa M, Lu D, Kondo JN, Hara M, Domen K, Hayashi S (2003) J Am Chem Soc 125(18):5479–5485
Li L, Ma R, Ebina Y, Iyi N, Sasaki T (2005) Chem Mater 17(17):4386–4391
Wang Q, O’Hare D (2012) Chem Rev 112(7):4124–4155
Ogino I, Nigra MM, Hwang S-J, Ha J-M, Rea T, Zones SI, Katz A (2011) J Am Chem Soc 133(10):3288–3291
Ouyang X, Hwang S-J, Runnebaum RC, Xie D, Wanglee Y-J, Rea T, Zones SI, Katz A (2014) J Am Chem Soc 136(4):1449–1461
Ogino I, Chen CY, Gates BC (2010) Dalton Trans 39(36):8423–8431
Lambert S, Job N, Dsouza L, Pereira M, Pirard R, Heinrichs B, Figueiredo J, Pirard J, Regalbuto J (2009) J Catal 261(1):23–33
Maheshwari S, Jordan E, Kumar S, Bates FS, Penn RL, Shantz DF, Tsapatsis M (2008) J Am Chem Soc 130(4):1507–1516
Eilertsen EA, Ogino I, Hwang SJ, Rea T, Yeh S, Zones SI, Katz A (2011) Chem Mater 23(24):5404–5408
Ogino I, Eilertsen EA, Hwang S-J, Rea T, Xie D, Ouyang X, Zones SI, Katz A (2013) Chem Mater 25(9):1502–1509
Paton KR, Varrla E, Backes C, Smith RJ, Khan U, O’Neill A, Boland C, Lotya M, Istrate OM, King P, Higgins T, Barwich S, May P, Puczkarski P, Ahmed I, Moebius M, Pettersson H, Long E, Coelho J, O’Brien SE, McGuire EK, Sanchez BM, Duesberg GS, McEvoy N, Pennycook TJ, Downing C, Crossley A, Nicolosi V, Coleman JN (2014) Nat Mater 13:624–630
Li D, Muller MB, Gilje S, Kaner RB, Wallace GG (2008) Nat Nano 3(2):101–105
Paredes JI, Villar-Rodil S, Martínez-Alonso A, Tascón JMD (2008) Langmuir 24(19):10560–10564
Su C, Loh KP (2012) Acc Chem Res 46(10):2275–2285
Haag D, Kung H (2014) Top Catal 57(6–9):762–773
Kamat PV (2009) J Phys Chem Lett 1(2):520–527
Seger B, Kamat PV (2009) J Phys Chem C 113(19):7990–7995
Li Y, Gao W, Ci L, Wang C, Ajayan PM (2010) Carbon 48(4):1124–1130
Li H, Song Z, Zhang X, Huang Y, Li S, Mao Y, Ploehn HJ, Bao Y, Yu M (2013) Science 342(6154):95–98
Joshi RK, Carbone P, Wang FC, Kravets VG, Su Y, Grigorieva IV, Wu HA, Geim AK, Nair RR (2014) Science 343(6172):752–754
Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Nature 442(7100):282–286
Ramanathan T, Abdala AA, Stankovich S, Dikin DA, Herrera-alonso M, Piner RD, Adamson DH, Schniepp HC, Chen X, Ruoff RS, Nguyen ST, Aksay IA, Prud’homme RK, Brinson LC (2008) Nat Nanotechnol 3(6):327–331
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, Nguyen ST, Ruoff RS (2007) Nature 448(7152):457–460
Yang X, Cheng C, Wang Y, Qiu L, Li D (2013) Science 341(6145):534–537
Lei Z, Mitsui T, Nakafuji H, Itagaki M, Sugimoto W (2014) J Phys Chem C 118(13):6624–6630
Park S, Ruoff RS (2009) Nat Nano 4(4):217–224
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS (2007) Carbon 45(7):1558–1565
Feng H, Cheng R, Zhao X, Duan X, Li J (2013) Nat Commun 4:1539
Chua CK, Pumera M (2014) Chem Soc Rev 43(1):291–312
Qiu L, Liu JZ, Chang SL, Wu Y, Li D (2012) Nat Commun 3:1241
Hummers WS, Offeman RE (1958) J Am Chem Soc 80(6):1339
Galande C, Gao W, Mathkar A, Dattelbaum AM, Narayanan TN, Mohite AD, Ajayan PM (2014) Part Part Syst Charact 31(6):619–638
Wang X, Bai H, Shi G (2011) J Am Chem Soc 133(16):6338–6342
Karim MR, Hatakeyama K, Matsui T, Takehira H, Taniguchi T, Koinuma M, Matsumoto Y, Akutagawa T, Nakamura T, Noro S-I, Yamada T, Kitagawa H, Hayami S (2013) J Am Chem Soc 135(22):8097–8100
Krishnamoorthy K, Veerapandian M, Yun K, Kim SJ (2013) Carbon 53:38–49
Guittonneau F, Abdelouas A, Grambow B, Huclier S (2010) Ultrason Sonochem 17(2):391–398
Pan S, Aksay IA (2011) ACS Nano 5(5):4073–4083
Ogino I, Yokoyama Y, Iwamura S, Mukai SR (2014) Chem Mater 26(10):3334–3339
Talyzin AV, Luzan SM, Szabó T, Chernyshev D, Dmitriev V (2011) Carbon 49(6):1894–1899
Mukai SR, Nishihara H, Tamon H (2004) Chem Commun 7:874–875
Ogino I, Kazuki S, Mukai SR (2014) J Phys Chem C 118(13):6866–6872
Tuinstra F, Koenig JL (1970) J Chem Phys 53(3):1126
Ferrari AC, Robertson J (2000) Phys Rev B 61(20):14095–14107
Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) Phys Rev Lett 97(18):187401
Cancado LG, Jorio A, Ferreira EH, Stavale F, Achete CA, Capaz RB, Moutinho MV, Lombardo A, Kulmala TS, Ferrari AC (2011) Nano Lett 11(8):3190–3196
Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) Chem Soc Rev 39(1):228–240
Dimiev AM, Tour JM (2014) ACS Nano 8(3):3060–3068
Acik M, Lee G, Mattevi C, Pirkle A, Wallace RM, Chhowalla M, Cho K, Chabal Y (2011) J Phys Chem C 115(40):19761–19781
Perrozzi F, Croce S, Treossi E, Palermo V, Santucci S, Fioravanti G, Ottaviano L (2014) Carbon 77:473–480
Mustafa L, Aliaksandra R, John FD, Jonathan NC (2013) Nanotechnology 24(26):265703
Acknowledgments
We acknowledge Mr. Junichi Nishimura and Mr. Kohei Kitano for their help in the measurements of Raman spectra. This research was supported by JSPS KAKENHI Grant Numbers 24656478 and 60625581.
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Ogino, I., Yokoyama, Y. & Mukai, S.R. Sonication-Free Exfoliation of Graphite Oxide via Rapid Phase Change of Water. Top Catal 58, 522–528 (2015). https://doi.org/10.1007/s11244-015-0391-z
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DOI: https://doi.org/10.1007/s11244-015-0391-z