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High-Performance Catalysts with MSE-Type Zeolite Framework

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Abstract

Advances on the preparation routes to MSE-type zeolites, microporous silicates with a 12-10-10-ring micropore system, are reviewed and some examples of the catalytic application are presented. MCM-68 as the most typical aluminosilicate material with the MSE framework synthesized by using a rigid and bulky diquaternary ammonium cation as the organic structure-directing agent exhibited excellent catalytic performance for hexane cracking and dimethyl ether-to-olefin reactions when it was post-synthetically dealuminated with nitric acid. Variation of the synthetic route provided characteristic aluminosilicate MSE-type materials with the improved catalytic performances for hexane cracking. Dealuminated MCM-68 was efficiently converted to titanosilicate [Ti]-MCM-68, which exhibited high catalytic performance in epoxidation and phenol oxidation. In addition, the pure-silica version of MSE framework, YNU-2, was successfully synthesized by dry-gel conversion method using the same organic cation followed by stabilization via steaming. To the remaining site defects in the stabilized framework of YNU-2, Ti atoms were introduced to give the new microporous titanosilicate [Ti]-YNU-2, which showed very high activity and para-selectivity during phenol oxidation using H2O2 as an oxidant.

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Acknowledgments

This work was financially supported in part by Adaptable and Seamless Technology Transfer Program through Target-driven R&D (A-STEP, AS231Z03507C) from Japan Science and Technology Agency (JST), by the New Energy and Industrial Technology Development Organization (NEDO), and by Grant-in-Aid for Scientific Research (Nos. 13199071 and 23760741).

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  1. Division of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan

    Y. Kubota & S. Inagaki

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  1. Y. Kubota
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  2. S. Inagaki
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Correspondence to Y. Kubota.

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Kubota, Y., Inagaki, S. High-Performance Catalysts with MSE-Type Zeolite Framework. Top Catal 58, 480–493 (2015). https://doi.org/10.1007/s11244-015-0389-6

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