Abstract
A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CH x and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CH x /CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.
Similar content being viewed by others
References
Armor JN (1999) Appl Catal A 176:159–176
Bshish A, Yakoob Z, Narayanan B, Ramakrishnan R, Ebshish A (2011) Chem Pap 65:251–266
Hernández L, Kafarov V (2009) Int J Hydrogen Energy 34:7041–7050
Mattos LV, Jacobs G, Davis BH, Noronha FB (2012) Chem Rev 112:4094–4123
Ni M, Leung DYC, Leung MKH (2007) Int J Hydrogen Energy 32:3238–3247
Xuan J, Leung MKH, Leung DYC, Ni M (2009) Renew Sustain Energy Rev 13:1301–1313
Wei ZH, Sun JM, Li Y, Datye AK, Wang Y (2012) Chem Soc Rev 41:7994–8008
Duan S, Senkan S (2005) Ind Eng Chem Res 44:6381–6386
Karim AM, Su Y, Sun JM, Yang C, Strohm JJ, King DL, Wang Y (2010) Appl Catal B-Environ 96:441–448
Choong CKS, Zhong Z, Huang L, Wang Z, Ang TP, Borgna A, Lin J, Hong L, Chen L (2011) Appl Catal A 407:145–154
Sun J, Qiu X-P, Wu F, Zhu W-T (2005) Int J Hydrogen Energy 30:437–445
Zhang B, Tang X, Li Y, Xu Y, Shen W (2007) Int J Hydrogen Energy 32:2367–2373
Padilla R, Benito M, Rodríguez L, Serrano A, Muñoz G, Daza L (2010) Int J Hydrogen Energy 35:8921–8928
Zhang B, Tang X, Li Y, Cai W, Xu Y, Shen W (2006) Catal Commun 7:367–372
Banach B, Machocki A, Rybak P, Denis A, Grzegorczyk W, Gac W (2011) Catal Today 176:28–35
Barton DG, Soled SL, Iglesia E (1998) Top Catal 6:87–99
Batista MS, Santos RKS, Assaf EM, Assaf JM, Ticianelli EA (2003) J Power Sources 124:99–103
Llorca J, Homs Ns, Sales J, de la Piscina PRr (2002) J Catal 209:306–317
Haga F, Nakajima T, Miya H, Mishima S (1997) Catal Lett 48:223–227
Song H, Zhang LZ, Watson RB, Braden D, Ozkan US (2007) Catal Today 129:346–354
Song H, Zhang LZ, Ozkan US (2010) Ind Eng Chem Res 49:8984–8989
Song H, Ozkan US (2009) J Catal 261:66–74
Song H, Ozkan US (2009) J Phys Chem A 114:3796–3801
Lin SSY, Kim DH, Ha SY (2009) Appl Catal a-Gen 355:69–77
Martono E, Hyman MP, Vohs JM (2011) Phys Chem Chem Phys 13:9880–9886
Martono E, Vohs JM (2011) ACS Catal 1:1414–1420
Martono E, Vohs JM (2012) J Catal 291:79–86
Hyman MP, Vohs JM (2011) Surf Sci 605:383–389
Karim AM, Su Y, Engelhard MH, King DL, Wang Y (2011) ACS Catal 1:279–286
Lebarbier VM, Karim AM, Engelhard MH, Wu Y, Xu B-Q, Petersen EJ, Datye AK, Wang Y (2011) ChemSusChem 4:1679–1684
Yue WB, Zhou WZ (2007) J Mater Chem 17:4947–4952
Mishra BG, Rao GR (2006) J Mol Catal a-Chem 243:204–213
Duclere JR, Doggett B, Henry MO, McGlynn E, Kumar RTR, Mosnier JP, Perrin A, Guilloux-Viry M (2007) J Appl Phys 101
O’Shea VAD, Homs N, Pereira EB, Nafria R, de la Piscina PR (2007) Catal Today 126:148–152
Khodakov AY, Griboval-Constant A, Bechara R, Zholobenko VL (2002) J Catal 206:230–241
Laguna OH, Centeno MA, Romero-Sarria F, Odriozola JA (2011) Catal Today 172:118–123
He Z, Yang M, Wang X, Zhao Z, Duan A (2012) Catal Today 194:2–8
Moura JS, Souza MOG, Bellido JDA, Assaf EM, Opportus M, Reyes P, Rangel MdC (2012) Int J Hydrogen Energy 37:3213–3224
Zhong Z, Ang H, Choong C, Chen L, Huang L, Lin J (2009) Phys Chem Chem Phys 11:872–880
Song H, Bao X, Hadad CM, Ozkan US (2011) Catal Lett 141:43–54
Hayashi F, Iwamoto M (2013) ACS Catal: 14–17
Sun J, Zhu K, Gao F, Wang C, Liu J, Peden CHF, Wang Y (2011) J Am Chem Soc 133:11096–11099
Acknowledgments
We acknowledge the financial support from the US Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, the WSU Franceschi Microscopy Center and Dr. Knoblauch for use of the TEM, and the WSU GeoAnalytical Lab and Dr. Rowe for use of the XRD. S.D. thanks Feng Gao and Yilin Wang for many helpful discussions in the early stage of this work.
Author information
Authors and Affiliations
Corresponding authors
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Davidson, S., Sun, J. & Wang, Y. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter. Top Catal 56, 1651–1659 (2013). https://doi.org/10.1007/s11244-013-0103-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-013-0103-5