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Pore Condensation in Glycerol Dehydration

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Abstract

Pore condensation followed by polymerization is proposed as an explanatory model of several observations reported in the literature regarding the dehydration of glycerol to acrolein. The major conclusion is that glycerol pore condensation in the micro- and mesopores, followed by polymerization in the pores, play a role in catalyst deactivation.

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Acknowledgments

The authors wish to thank Prof. Ingemar Odenbrand for critically reviewing the paper and giving feedback and Mrs. Birgitta Lindén for performing BET and MIP analysis. The financial support from the Swedish gas centre and the Swedish knowledge centre for renewable transportation fuels are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Lund University, P.O. Box 124, 221 00, Lund, Sweden

    Christian Hulteberg

  2. Biofuel-Solution AB, Box 300 84, 200 61, Limhamn, Sweden

    Andreas Leveau & Jan Gunnar Meo Brandin

Authors
  1. Christian Hulteberg
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  2. Andreas Leveau
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  3. Jan Gunnar Meo Brandin
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Correspondence to Christian Hulteberg.

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Hulteberg, C., Leveau, A. & Brandin, J.G.M. Pore Condensation in Glycerol Dehydration. Top Catal 56, 813–821 (2013). https://doi.org/10.1007/s11244-013-0039-9

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  • DOI: https://doi.org/10.1007/s11244-013-0039-9

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