Abstract
Current CuZnO methanol synthesis technology may be improved by development of a catalyst allowing a “once through” methanol synthesis step. A Raney copper/alkoxide catalyst has been reported in the patent literature operating at 50 bar and 120 °C. We report here the effect of temperature, pressure, Raney copper concentration and CH3OK concentration by orthogonal array design on this catalyst system. A synergistic effect on catalyst activity and methanol formation has been observed between CH3OK and Raney copper.
Similar content being viewed by others
References
Olah GA (2005) Angew Chem Int Ed 44:2636
Hansen JB, Højlund Nielsen PE (2008) In: Ertl G, Knözinger H, Schüth F, Weitkamp J (eds) Handbook of heterogeneous catalysis, vol 6. Wiley, Weinheim, p 2920
Christiansen JA (1919) US Patent 1,302,011, 29 April 1919)
Turek T, Trimm DL (1994) Catal Rev Sci Eng 36:645
Sapienza RS, Slegeir WA, O’Hare TE, Mahajan D (1986) US Patent 4,614,749, 30 Sept 1986
Stahler A (1914) Ber Deutsch Chem Ges 47:580
Ohyama S (2006) Appl Catal A 313:58
Ohyama S (2000) Stud Surf Sci Catal 130:3753
Curry-Hyde HE, Wainwright MS, Young DY (1988) Stud Surf Sci Catal 36:239
Kokubu Y, Fujiwara K, Ono H, Sugawara H, Yamamoto K, Oomatsuzawa T, Inomata M (2000) US Patent 6,028,119, 22 Feb 2000
Hedayat AS, Stufken J, Neil Sloane JA (1999) Orthogonal arrays: theory and applications. Springer, New York, p 317
Sørum PA, Onsager OT (1984) 8th International congress on catalysis. DECHEMA and Verlag Chemie, Weinheim, p II-233
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, B., Jens, K.J. Liquid-Phase Low-Temperature and Low-Pressure Methanol Synthesis Catalyzed by a Raney Copper-Alkoxide System. Top Catal 56, 725–729 (2013). https://doi.org/10.1007/s11244-013-0031-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-013-0031-4