Abstract
Acid functionalized activated carbon was studied as a catalyst in xylose dehydration. It was compared with commonly used solid acid catalysts, H-mordenite and TiO2. The carbon surface was modified with H2SO4 and/or HNO3 treatment, resulting in highly active and selective dehydration catalysts that were stable in aqueous reaction conditions.
Similar content being viewed by others
References
Lin Y-C, Huber GW (2009) Energy Environ Sci 2:68
Stöcker M (2008) Angew Chem Int Ed 47:9200
Corma A, Iborra S, Velty A (2007) Chem Rev 107:2411
Chheda JN, Huber GW, Dumesic JA, Angew (2007) Chem. Int. Ed. 46:7164
Kooststra AMJ, Mosier NS, Scott EL, Beeftink HH (2009) Biochem Eng J 43:92
Nabarlatz D, Farriol X, Montané D (2004) Ind Eng Chem Res 43:4124
Karinen R, Vilonen K, Niemelä M (2011) ChemSusChem 4:1002
Lam E, Chong JH, Majid E, Liu Y, Hrapovic S, Leung ACW, Luong JHT (2012) Carbon 50:1033
Weingarten R, Tompsett GA, Conner WC Jr, Huber GW (2011) J. Cat. 279:174
Okuhara T (2002) Chem Rev 102:3641
Kabalka GW, Pagni RM (1997) Tetrahdedron 53:7999
Figueiredo JL, Pereira MFR (2010) Cat. Today 150:2
Toebes ML, van Heeswijk JMP, Bitter JH, van Dillen AJ, de Jong KP (2004) Carbon 42:307
Dias AS, Pillinger M, Valente AA (2005) J Catal 229:414
Gregg SJ, Sing KSW (1982) Adsorption Surface Area and Porosity, 2nd edn. Academic Press, New York, p 303
Brunauer S, Emmett PH, Teller E (1938) J Am Chem Soc 60(2):309–380
Barrett EP, Joyner LG, Halenda PP (1951) J Am Chem Soc 73(1):373–380
Oickle AM, Goertzen SL, Hopper KR, Abdalla YO (2010) Carbon 48:3313
Salame IS, Bandosz TJ, Colloid J (2001) Interface Sci 240:252
Onda A, Ochi T, Yanagisawa K (2008) Green Chem 10:1033
Ranjan R, Thust S, Chrysanthos CE, Gounaris E, Woo M, Floudas CA, von Keitz M, Valentas KJ, Wei J, Tsapatsis M (2009) Microporous Mesoporous Mat. 122:143
Ordomsky VV, van der Schaaf J, Schouten JC, Nijhuis TA (2012) ChemSusChem 5:1812
Papp J, Soled S, Dwight K, Wold A (1994) Chem Mater 6:496
Terzyk AP, Colloid J (2003) Interface Sci 268:301
Hadjivanov KI, Klissurski DG (1996) Chem Soc Rev 1:61
Sun F, Zhou W, Tian G, Pan K, Miao X, Li Y, Zhang G, Li T, Fu H (2012) ChemCatChem 4:844
Akiya N, Savage PE (2002) Chem Rev 102:2725
Moreau C, Durand R, Peyron D, Duhamet J, Rivalier P (1998) Ind Crops Prod 7:95
Takagaki A, Ohara M, Nishimura S, Ebitani K (2010) Chem Lett 39:838
Marcotullio G, De Jong W (2010) Green Chem 12:1739
O’Neil R, Ahmad MN, Vanoye L, Aiouache F (2009) Ind Eng Chem Res 48:4300
Aguado-Serrano J, Rojas-Cervantes ML (2006) Microporous Mesoporous Mat. 88:205
O’Neill R, Ahmad MN, Vanoye L, Aiouache F (2009) Ind Eng Chem Res 48:4300
Zholobenko VL, Makarova MA, Dwyer J (1993) J Phys Chem 97:5962
Takagaki, Ohara M, Nishimura S, Ebitani K (2010) Chem Lett 39:838–840
Watanabe M, Aizawa Y, Ida T, Nishimura R, Inomata H (2005) Appl. Cat. A 295:150–156
Dias AS, Lim S, Pillinger M, Valente AA (2007) Catal Lett 114:151
Acknowledgments
The CNB-E project of the Multidisciplinary Institute of Digitalization and Energy (MIDE) program is acknowledged for its financial support. Christa Bonde Jensen, Joonas Likander, and Sergio Gonzalez Rodriguez are acknowledged for their experimental assistance.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Sairanen, E., Vilonen, K., Karinen, R. et al. Functionalized Activated Carbon Catalysts in Xylose Dehydration. Top Catal 56, 512–521 (2013). https://doi.org/10.1007/s11244-013-0013-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-013-0013-6