Abstract
The effect of potassium, sodium and water on Fe–ZSM-5, W–ZSM-5 and ZSM-5 catalysts was investigated. Catalysts were characterized by several techniques and tested in the NH3-SCR reaction. The impact of water-, K- and Na-treatments on the activity of catalysts was negligible. Thus, the catalysts can be concluded to be resistant to K- and Na-treatments.
Similar content being viewed by others
References
Directive 2003/30/EC of the European Parliament and of the Council
Directive 2009/28/EC of the European Parliament and of the Council
Xue J, Grift TE, Hansen AC (2011) Renew Sustain Energy Rev 15:1098
Ham SW, Nam IS (2002) In: Spivey JJ (ed) Catalysis, vol 16. Royal Society of Chemistry, Cambridge
Koebel M, Elsener M, Kleemann M (2000) Catal Today 59:335
Alemany LJ, Lietti L, Ferlazzo N, Forzatti P, Busca G, Giamello E, Bregani F (1995) J Catal 155:117
Choo ST, Yim SD, Nam IS, Ham SW, Lee JB (2003) Appl Catal B 44:237
Kröcher O, Elsener M (2008) Ind Eng Chem 47:8588
Jiang L, Ge Y, Naeem Shah A, He C, Liu Z (2010) J Environ Sci 22(4):575
Roy S, Hegde MS, Madras G (2009) Appl Energy 86:2283
Kamata H, Takahashi K, Odenbrand CUI (1999) J Mol Catal A 139:189
Zheng Y, Jensen AD, Johnsson JE (2005) Appl Catal B 60:253
Kröcher O, Elsener M (2008) Appl Catal B 75:215
Klimczak M, Kern P, Heinzelmann T, Lucas M, Claus P (2010) Appl Catal B 95:39
Tang F, Xu B, Shi H, Qiu J, Fan Y (2010) Appl Catal B 94:71
Putluru SSR, Kristensen SB, Buus S, Due-Hansen J, Riisager A, Fehrmann R (2012) Top Catal 184:192
Cuiping L, Chuangzhi W, Yanyongjie, Haitao H (2004) Biomass Bioenerg 27:119
Obernberger I, Brunner T, Bärnthaler G (2006) Biomass Bioenerg 30:973
Monti A, Di Virgilio N, Venturi G (2008) Biomass Bioenerg 32:216
Schwidder M, Kumar MS, Klementiev K, Pohl MM (2005) J Catal 231:314
Qi G, Yang RT (2005) Appl Catal B 60:13
Kröcher O, Devadas M, Elsener M, Wokaun A, Söger N, Pfeifer M, Demel Y, Mussmann L (2006) Appl Catal B 66:208
Grossale A, Nova I, Tronconi E (2008) Catal Today 136:18
Brandenberger S, Kröcher O, Tissler A, Althoff R (2010) Appl Catal B 95:348
Shi X, Liu F, Shan W, He H (2012) Chin J Catal 33:454
Kern P, Klimczak M, Heinzelmann T, Lucas M, Claus P (2010) Appl Catal B 95:48
Putluru SSR, Jensen AD, Riisager A, Fehrmann R (2011) Top Catal 54:1286
Peng Y, Li J, Chen L, Chen J, Han J, Zhang H, Han W (2012) Environ Sci Technol 46:2864
Lee SM, Kim SS, Hong SC (2012) Chem Eng Sci 79:177
Nova I, Lietti L, Casagrande L, Dall’Acqua L, Giamello E, Forzatti P (1998) Appl Catal B 17:245
Wang X, Zhang S, Yu Q, Yang H (2008) Microporous Mesoporous Mater 109:298
Grossale A, Nova I, Tronconi E, Chatterjee D, Weibel M (2008) J Catal 256:312
Devadas M (2006) Selective catalytic reduction (SCR) of nitrogen oxides with ammonia over Fe-ZSM5. Doctoral dissertation. University Erlangen-Nürenberg, Zurich
Kim MH, Ham SW (2010) Top Catal 53:597
Toops TJ, Smith DB, Epling WS, Parks JE, Partridge WP (2005) Appl Catal B 58:255
Li Q, Meng M, Dai F, Zha Y, Xie Y, Hu T, Zhang J (2012) Chem Eng J 184:106
Long RQ, Yang RT (2002) J Catal 207:224
Metkar PS, Harold MP, Balakotaiah V (2013) Chem Eng Sci 87:51
Long RQ, Yang RT (2000) J Catal 194:80
Chen HY, El-Malki EM, Wang X, van Santen RA, Sachtler WMH (2000) J Mol Catal A 162:159
Devadas M, Kröcher O, Elsener M, Wokaun A, Mitrikas G, Söger N, Pfeifer M, Demel Y, Mussmann L (2007) Catal Today 119:137
Rahkamaa-Tolonen K, Maunula T, Lomma M, Huuhtanen M, Keiski RL (2005) Catal Today 100:217
Devadas M, Kröcher O, Elsener M, Wokaun A, Söger N, Pfeifer M, Demel Y, Mussmann L (2006) Appl Catal B 67:187
Colombo M, Nova I, Tronconi E (2010) Catal Today 151:223
Iwasaki M, Shinjoh H (2010) Appl Catal A 390:71
Luo JY, Hou X, Wijayakoon P, Schmieg SJ, Li W, Epling WS (2011) Appl Catal B 102:110
Long RQ, Yang RT (2000) Chem Commun 17:1651
Salker AV (2004) Indian J Chem Technol 11:683
Acknowledgments
This study has been carried out with the financial support from Tekes, the Finnish Funding Agency for Technology and Innovation, via the Cleen Ltd’s Future Combustion Engine Power Plant (FCEP) -programme.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Väliheikki, A., Kolli, T., Huuhtanen, M. et al. The Effect of Biofuel Originated Potassium and Sodium on the NH3-SCR Activity of Fe–ZSM-5 and W–ZSM-5 Catalysts. Top Catal 56, 602–610 (2013). https://doi.org/10.1007/s11244-013-0012-7
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11244-013-0012-7