Abstract
Catalytic and thermal conversion of abietic acid was investigated in a laboratory scale high-pressure autoclave. Fractionation of crude tall oil produces rosin acids of which abietic acid is the main compound. Tall oil rosin acid, a forest product industry residue, is an abundant, inexpensive and chemically desirable feedstock for production of lighter hydrocarbons that can be used as diesel fuel additives. The carboxylic acid functionality of the main reactant, abietic acid, must first be removed, followed by double bond hydrogenation of the remaining aromatic rings. In this study, a number of catalytic and non-catalytic reaction steps in the conversion of abietic acid were investigated. The aim was to study hydrogenation and decarboxylation reactions of abietic acid in order to produce lighter hydrocarbons. The experiments were performed by using toluene as a solvent as well as with neat abietic acid, in the absence of any solvent. Hydrogenation of abietic acid to tetrahydroabietic acid in toluene was successfully performed over palladium on carbon catalyst at the temperature range of 100–200 °C and at 30 bar hydrogen pressure. Thermal non-catalytic decarboxylation of abietic acid in toluene takes place at 200–300 °C resulting in one main product. The hydrocarbon products were further hydrogenated under hydrogen pressure. Catalytic decarboxylation of abietic acid in toluene was achieved over 5 wt% Ru/C, giving a wider product distribution than thermal decarboxylation.
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References
Coll R, Udas S, Jacoby WA (2001) Conversion of the rosin acid fraction of crude tall oil into fuels and chemicals. Energy Fuels 15:1166–1172
Portugal I, Domingues C, Valentine A (2005) Rosin disproportionation: catalytic testing and modelling, 2nd mercosur congress on chemical engineering, 4th Mercosur Congress on Process System Engineering, Brasil, 2005
Wang L, Chen X, Liang J, Chen Y, Pu X, Tong Z (2009) Kinetics of the catalytic isomerization and disproportionation of rosin over carbon-supported palladium. Chem Eng J 152:242–250
Souto JC, Yustod P, Ladero M, Garica-Ochoa F (2011) Disproportionation of rosin on an industrial Pd/C Catalyst: reaction pathway and kinetic model discrimination. Bioresour Technol 102:3504–3511
Bernas A, Kumar N, Mäki-Arvela P, Holmbom B, Salmi T, Murzin DYu (2004) Heterogeneous catalytic production of conjugated linoleic acid. Org Process Res Dev 8:341–352
Acknowledgments
This work is part of the activities at the Åbo Akademi Process Chemistry Centre within the Finnish Centre of Excellence Programme (2000–2011) by the Academy of Finland. The Finnish Agency for Technology and Innovations (TEKES) and Forchem Oy are gratefully acknowledged for financial support. In Sweden, the Biorefinery Programme is acknowledged. Further, the COST—action CM0903 is recognized.
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Bernas, A., Salmi, T., Murzin, D.Y. et al. Catalytic Transformation of Abietic Acid to Hydrocarbons. Top Catal 55, 673–679 (2012). https://doi.org/10.1007/s11244-012-9846-7
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DOI: https://doi.org/10.1007/s11244-012-9846-7