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Tuning the Behavior of Au and Pt Catalysts for the Chemoselective Hydrogenation of Nitroaromatic Compounds

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Abstract

Efficient catalysts for the synthesis of functionalized anilines from the corresponding substituted nitroaromatics should combine an excellent chemoselectivity with a high hydrogenation activity. Attempts to increase the activity of the Au/TiO2 catalyst and to improve the selectivity of traditional Pt catalysts, based on a previous understanding of the mode of action of supported gold and platinum nanoparticles, are reviewed and discussed.

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Acknowledgment

We thank Consolider-Ingenio-2010 (project MULTICAT) for financial support.

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Authors and Affiliations

  1. Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia. Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022, Valencia, Spain

    Pedro Serna, Mercedes Boronat & Avelino Corma

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  1. Pedro Serna
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  2. Mercedes Boronat
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  3. Avelino Corma
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Correspondence to Avelino Corma.

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Serna, P., Boronat, M. & Corma, A. Tuning the Behavior of Au and Pt Catalysts for the Chemoselective Hydrogenation of Nitroaromatic Compounds. Top Catal 54, 439–446 (2011). https://doi.org/10.1007/s11244-011-9668-z

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