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CuFe2O4 Nanoparticles: A Magnetically Recoverable Catalyst for Selective Deacetylation of Carbohydrate Derivatives

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Abstract

An efficient protocol for the rapid room temperature deacetylation of carbohydrate derivatives using CuFe2O4 nanoparticles as an inexpensive and reusable catalyst is presented. After separation of the catalyst with an external magnet, the reaction products are easily obtained in good purity and excellent yields.

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References

  1. Greene TW, Wuts PGM (1999) Protective groups in organic synthesis. Wiley, New York, pp 149–160 (and references cited therein)

    Book  Google Scholar 

  2. Zemplen G, Pacsu E (1929) Ber Dtsch Chem Ges 62:1613

    Article  Google Scholar 

  3. Helferich B, Portz W (1953) Chem Ber 86:604

    Article  CAS  Google Scholar 

  4. Excoer G, Gagnaire D, Utille JP (1975) Carbohydr Res 39:368

    Article  Google Scholar 

  5. Rowell RM, Feather MS (1967) Carbohydr Res 4:486

    Article  CAS  Google Scholar 

  6. Tuan Tran A, Deydier S, Bonnae D, Le Narvor C (2008) Tetrahedron Lett 49:2163

    Article  Google Scholar 

  7. Kunesch N, Meit C, Poisson J (1987) Tetrahedron Lett 28:3569

    Article  CAS  Google Scholar 

  8. Yanada R, Negoro N, Bessho K, Yanada K (1995) Synlett 12:1261

    Article  Google Scholar 

  9. Baptistella LHB, dos Santos JF, Ballabio KC, Marsaioli AJ (1989) Synthesis 6:436

    Article  Google Scholar 

  10. Yamamoto N, Nishikawa T, Isobe M (1995) Synlett (Special Issue):505

  11. Pozsgay V, Coxon B (1993) Carbohydr Res 257:189

    Article  Google Scholar 

  12. Gonzalez AG, Brouard I, Leon F, Padron JI, Bermejo J (2001) Tetrahedron Lett 42:3187

    Article  CAS  Google Scholar 

  13. Trost BM, Frederiksen MU, Rudd MT (2005) Angew Chem Int Ed 44:6630

    Article  CAS  Google Scholar 

  14. Abu-Reziq R, Alper H, Wang D, Post ML (2006) J Am Chem Soc 128:5279

    Article  CAS  Google Scholar 

  15. Zang D-H, Li G-D, Li J-X, Chen J-S (2008) Chem Commun 29:3414

    Article  Google Scholar 

  16. Shokouhimehr M, Piao Y, Kim J, Jang Y, Hyeon T (2007) Angew Chem Int Ed 46:7039

    Article  CAS  Google Scholar 

  17. Lu A-H, Salabas EL, Schuth F (2007) Angew Chem Int Ed 46:1222

    Article  CAS  Google Scholar 

  18. Chaubal NS, Joshi VY, Sawant MR (2007) J Mol Catal A 267:157

    Article  CAS  Google Scholar 

  19. Mojtahedi MM, Abaee MS, Alishiri T (2009) Tetrahedron Lett 50:2322

    Article  CAS  Google Scholar 

  20. Mojtahedi MM, Abaee MS, Eghtedari M (2008) Appl Organomet Chem 22:529

    Article  CAS  Google Scholar 

  21. Sartori G, Ballini R, Bigi F, Bosica G, Maggi R, Righi P (2004) Chem Rev 104:199

    Article  CAS  Google Scholar 

  22. Tao S, Gao F, Liu X, Sørensen OT (2000) Mater Sci Eng B 77:172

    Article  Google Scholar 

  23. George M, John AM, Nair SS, Joy PA, Anantharam MR (2006) J Magn Magn Mater 302:190

    Article  CAS  Google Scholar 

  24. Herzig J, Nudelman A, Gottlieb HE, Fischer B (1986) J Org Chem 51:727

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Authors thank to Comisión de Investigaciones Científicas de la Provincia de Buenos Aires (CICPBA), CONICET, UNCPBA and UNLP for their financial support to the present work.

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Authors and Affiliations

  1. Facultad de Ingeniería, UNCPBA, Av. Del valle 5737, Olavarría, Argentina

    Julia E. Tasca & Araceli Lavat

  2. Laboratorio de Estudio de Compuestos Orgánicos (LADECOR), Departamento de Química, Facultad de Ciencias Exactas, UNLP, 47 y 115, B1900AJL, La Plata, Argentina

    Agustín Ponzinibbio, Gisela Diaz & Rodolfo D. Bravo

  3. Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. Jorge Ronco” (CINDECA), CONICET—UNLP, Calle 47 N 257, B1900AJK, La Plata, Argentina

    María G. González

Authors
  1. Julia E. Tasca
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  2. Agustín Ponzinibbio
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  3. Gisela Diaz
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  4. Rodolfo D. Bravo
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  5. Araceli Lavat
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  6. María G. González
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Corresponding author

Correspondence to María G. González.

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Tasca, J.E., Ponzinibbio, A., Diaz, G. et al. CuFe2O4 Nanoparticles: A Magnetically Recoverable Catalyst for Selective Deacetylation of Carbohydrate Derivatives. Top Catal 53, 1087–1090 (2010). https://doi.org/10.1007/s11244-010-9538-0

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  • DOI: https://doi.org/10.1007/s11244-010-9538-0

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