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Effect of Counter-Ion on Recycle of Polymer Resin Supported Co(III)-Salen Catalysts in the Hydrolytic Kinetic Resolution of Epichlorohydrin

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Abstract

New polymer supported Co(III)-salen-X (X = acetate, camphorsulfonate, BF4) catalysts with different counter-ions are synthesized and evaluated in the hydrolytic kinetic resolution of epichlorohydrin. The polymer resin supported catalysts are effectively recovered after reaction by filtration and reused in subsequent reactions with similar selectivity. The recycled catalysts give decreased reaction rates, and the deactivation is dependent on the counter-ion.

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Acknowledgements

The US DOE Office of Basic Energy Science is acknowledged for financial support through Catalysis Contract No. DEFG02-03ER15459.

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Authors and Affiliations

  1. School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, 30332, USA

    Krishnan Venkatasubbaiah, Xun-Jin Zhu & Christopher W. Jones

Authors
  1. Krishnan Venkatasubbaiah
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  2. Xun-Jin Zhu
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  3. Christopher W. Jones
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Corresponding author

Correspondence to Christopher W. Jones.

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Venkatasubbaiah, K., Zhu, XJ. & Jones, C.W. Effect of Counter-Ion on Recycle of Polymer Resin Supported Co(III)-Salen Catalysts in the Hydrolytic Kinetic Resolution of Epichlorohydrin. Top Catal 53, 1063–1065 (2010). https://doi.org/10.1007/s11244-010-9533-5

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  • DOI: https://doi.org/10.1007/s11244-010-9533-5

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