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Ammonia IRMS-TPD Characterization of Brønsted Acid Sites in Medium-pore Zeolites with Different Framework Topologies

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Abstract

Brønsted acidity in a series of zeolites with 8- and/or 10-rings (clinoptilolite, TNU-10, SUZ-4, ZSM-57, ZSM-5, TNU-9, and IM-5) was characterized by the ammonia infrared/mass spectroscopy-temperature-programmed desorption (IRMS-TPD) technique. The zeolites with mutually intersecting 10-ring channels were found to have lower acid strength than those with intersecting 10- and 8-ring channels.

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Acknowledgments

Funding for this work was provided by the Korea Science and Engineering Foundation through the National Research Laboratory Program (R0A-2007-000-20050-0) and Grant-in-Aids for Scientific Research from Japan Society for the Promotion of Science (A 08636016, C 20560721, and B 21360396).

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Authors and Affiliations

  1. Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, 4-101 Koyama-cho Minami, Tottori, 680-8552, Japan

    Naonobu Katada, Katsuki Suzuki, Takayuki Noda & Miki Niwa

  2. Japan Society for the Promotion of Science, Chiyoda-ku, Tokyo, 102-8471, Japan

    Katsuki Suzuki

  3. Department of Chemical Engineering and School of Environmental Science and Engineering, POSTECH, Pohang, 790-784, Korea

    Min Bum Park, Hyung-Ki Min & Suk Bong Hong

Authors
  1. Naonobu Katada
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  2. Katsuki Suzuki
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  3. Takayuki Noda
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  4. Min Bum Park
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  5. Hyung-Ki Min
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  6. Suk Bong Hong
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  7. Miki Niwa
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Correspondence to Naonobu Katada or Suk Bong Hong.

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Katada, N., Suzuki, K., Noda, T. et al. Ammonia IRMS-TPD Characterization of Brønsted Acid Sites in Medium-pore Zeolites with Different Framework Topologies. Top Catal 53, 664–671 (2010). https://doi.org/10.1007/s11244-010-9503-y

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  • DOI: https://doi.org/10.1007/s11244-010-9503-y

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