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Surface Base Sites of MgO Covered with Al2O3: XANES Analysis of Al and Mg K-edges

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Abstract

Solid bases comprising MgO covered with Al2O3 were prepared by decomposition of Al(OCH(CH3)2)3 over Mg(OH)2 in ethyl acetate. Catalysts containing more than 10 mol% Al were insoluble in acetone. Aluminum occupied mainly octahedral sites in the low content range; tetrahedral structure being the principal one in the high range.

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Authors and Affiliations

  1. Department of Science, Hokkaido University of Education, 1-2 Hachiman-cho, Hakodate, 040-8567, Japan

    Hiromi Matsuhashi

  2. Department of Life Science & Green Chemistry, Faculty of Engineering, Saitama Institute of Technology, 1690 Fusaiji, Fukaya, 369-0293, Japan

    Koji Nagashima, Nobuaki Naijo & Hirofumi Aritani

Authors
  1. Hiromi Matsuhashi
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  2. Koji Nagashima
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  3. Nobuaki Naijo
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  4. Hirofumi Aritani
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Correspondence to Hiromi Matsuhashi.

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Matsuhashi, H., Nagashima, K., Naijo, N. et al. Surface Base Sites of MgO Covered with Al2O3: XANES Analysis of Al and Mg K-edges. Top Catal 53, 659–663 (2010). https://doi.org/10.1007/s11244-010-9502-z

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  • DOI: https://doi.org/10.1007/s11244-010-9502-z

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