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Photocatalytic Cancer (HeLa) Cell-Killing Enhanced with Cu–TiO2 Nanocomposite

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Abstract

The metallic Cu nanoparticles have been successfully deposited on the heterogeneous TiO2 surface by the borohydride reduction of copper nitrate in water/CH3CN mixture under Ar atmosphere. The catalytic activity of the Cu–TiO2 nanocomposite was evaluated by the application to a photocatalytic cancer cell-killing under UV–visible light irradiation. Based on the obtained results, a plausible mechanism was proposed.

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References

  1. Anpo M, Takeuchi M (2003) J Catal 216:505

    Article  CAS  Google Scholar 

  2. Dawson A, Kamat PV (2001) J Phys Chem B 105:960

    Article  CAS  Google Scholar 

  3. Bowker M, James D, Stone P, Bennett R, Perkins N, Millard L, Greaves J, Dickinson A (2003) J Catal 217:427

    CAS  Google Scholar 

  4. Herrmann JM, Disdier J, Pichat P (1988) J Catal 113:72

    Article  CAS  Google Scholar 

  5. Stathatos E, Lianos P, Falaras P, Siokou A (2000) Langmuir 16:2398

    Article  CAS  Google Scholar 

  6. Schaaff TG, Blom DA (2002) Nano Lett 2:507

    Article  CAS  Google Scholar 

  7. Sun B, Vorontsov AV, Smirniotis PG (2003) Langmuir 19:3151

    Article  CAS  Google Scholar 

  8. Kim S, Choi W (2002) J Phys Chem B 106:13311

    Article  CAS  Google Scholar 

  9. Jeon S, Braun PV (2003) Chem Mater 15:1256

    Article  CAS  Google Scholar 

  10. Klosek S, Raftery D (2001) J Phys Chem B 105:2815

    Article  CAS  Google Scholar 

  11. Patra A, Friend CS, Kapoor R, Prasad PN (2003) Chem Mater 15:3650

    Article  CAS  Google Scholar 

  12. Premkumar J (2004) Chem Mater 16:3980

    Article  CAS  Google Scholar 

  13. Bryan JD, Heald SM, Chambers SA, Gamelin DR (2004) J Am Chem Soc 126:11640

    Article  CAS  Google Scholar 

  14. Kamat PV (1993) Chem Rev 93:267

    Article  CAS  Google Scholar 

  15. Bard JA (1982) J Phys Chem 86:172

    Article  CAS  Google Scholar 

  16. Burgeth G, Kisch H (2002) Coord Chem Rev 230:40

    Article  Google Scholar 

  17. Wood A, Giersig M, Mulvaney P (2001) J Phys Chem B 105:8810

    Article  CAS  Google Scholar 

  18. Jakob M, Levanon H, Kamat PV (2003) Nano Lett 3:353

    Article  CAS  Google Scholar 

  19. Subramanian V, Wolf EE, Kamat PV (2003) J Phys Chem B 107:7479

    Article  CAS  Google Scholar 

  20. Choi JY, Kim KH, Choy KC, Oh KT, Kim KN (2007) J Biomed Mater Res A 2:353

    Google Scholar 

  21. Cai R, Kubota Y, shuin T, Sakai H, Hashimoto K, Fujishima A (1992) Cancer Res 52:2346

    CAS  Google Scholar 

  22. Xu ZP, Zeng QH, Lu GQ, Yu AB (2006) Chem Eng Sci 61:1027

    Article  CAS  Google Scholar 

  23. Bideau M, Claudel B, Faure L, Rachimoellah M (1990) Chem Eng Commun 93:167

    Article  CAS  Google Scholar 

  24. Okamoto KI, Yamamoto Y, Tanaka H, Tanaka M, Itaya A (1985) Bull Chem Soc Jpn 58:2015

    Article  CAS  Google Scholar 

  25. Hufschmidt D, Bahnemmann D, Testa JJ, Emilio CA, Litter MI (2002) J Photochem Photobiol A 148:223

    Article  CAS  Google Scholar 

  26. Abdulla-Al-Mamun M, Kusumoto Y (2009) Chem Lett 38:826

    Article  CAS  Google Scholar 

  27. Abdulla-Al-Mamun M, Kusumoto Y, Muruganandham M (2009) Mater Lett 63:2007

    Article  CAS  Google Scholar 

  28. Wagner CD, Riggs WM, Davis LE, Moulder SF, Mullenberg GE (1979) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corporation, Physical Electronics Division, New York

    Google Scholar 

  29. Subramanian V, Wolf EE, Kamat PV (2004) J Am Chem Soc 126:4943

    Article  CAS  Google Scholar 

  30. Harbour JR, Tromp J, Hair ML (1985) Can J Chem 63:204

    Article  CAS  Google Scholar 

  31. Fujihira M, Satoh Y, Osa T (1981) Nature 293:206

    Article  CAS  Google Scholar 

  32. Linsebigler AL, Lu G, Yates JT Jr (1995) Chem Rev 95 735

  33. Abdulla-Al-Mamun M, Kusumoto Y, Mihata A, Islam MS, Ahmmad B (2009) Photochem Photobiol Sc. 8:1125

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The present work was partly supported by Grant-in-Aid for Scientific Research (B) (19360367) from Japan Society for the Promotion of Science (JSPS). The authors wish to thank Prof. Junichi Kurawaki for his informative discussions.

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Correspondence to Yoshihumi Kusumoto.

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Abdulla-Al-Mamun, M., Kusumoto, Y., Ahmmad, B. et al. Photocatalytic Cancer (HeLa) Cell-Killing Enhanced with Cu–TiO2 Nanocomposite. Top Catal 53, 571–577 (2010). https://doi.org/10.1007/s11244-010-9489-5

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  • DOI: https://doi.org/10.1007/s11244-010-9489-5

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