Skip to main content
SpringerLink
Log in

Convenient Synthesis of Mesoporous Aluminosilicates by Using Pre-heated Sodium Aluminosilicate Gel

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

Hydrothermally stable Al-MCM-48 with variety of Si/Al ratios and Al-MCM-41 with tunable pore sizes were successfully obtained from pre-heated aluminosilicate gel precursor. They showed the higher acid strength and hydrothermal stability comparing with conventional ones. Thus, this synthetic strategy offers a straightforward and convenient access to mesoporous aluminosilicates with zeolite-like acidity and stability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710

    Article  CAS  Google Scholar 

  2. Wan Y, Zhao D (2007) Chem Rev 107:2821

    Article  CAS  Google Scholar 

  3. Moller K, Bein T (1998) Chem Mater 10:2950

    Article  CAS  Google Scholar 

  4. Corma A (1997) Chem Rev 97:2373

    Article  CAS  Google Scholar 

  5. Kloetstra KR, Bekkum H, Jansen JC (1997) Chem Commun 23:2281

    Article  Google Scholar 

  6. Mokaya R, Jones W (1997) Chem Commun 22:2185

    Article  Google Scholar 

  7. Liu Y, Zhang W, Pinnavaia TJ (2000) J Am Chem Soc 122:8791

    Article  CAS  Google Scholar 

  8. Zhang ZT, Han Y, Zhu L, Wang RW, Yu Y, Qiu SL, Zhao DY, Xiao FS (2001) Angew Chem Int Ed 40:1258

    Article  CAS  Google Scholar 

  9. On DT, Kaliaguine S (2001) Angew Chem Int Ed 40:3248

    Article  CAS  Google Scholar 

  10. Fang Y, Hu H (2006) J Am Chem Soc 128:10636

    Article  CAS  Google Scholar 

  11. Zheng J, Kong D, Yang W, Xie Z, Wu D, Sun Y (2007) J Solid State Chem 180:564

    Article  CAS  Google Scholar 

  12. Ogura M, Zhang Y, Elangovan SP, Okubo T (2007) Microporous Mesoporous Mater 101:224

    Article  CAS  Google Scholar 

  13. Liu Y, Pinnavaia TJ (2002) J Mater Chem 12:3179

    Article  CAS  Google Scholar 

  14. Jun S, Kim JM, Ryoo R, Ahn Y-S, Han M-H (2000) Microporous Mesoporous Mater 41:119

    Article  CAS  Google Scholar 

  15. Xia Q-H, Hidajat K, Kawi S (2001) Chem Lett 30:654

    Article  Google Scholar 

  16. Sun J-H, Coppens M-O (2002) J Mater Chem 12:3016

    Article  CAS  Google Scholar 

  17. Campelo JM, Luna D, Luque R, Marinas JM, Romero AA, Calvino JJ, Rodriguez-Luque MP (2005) J Catal 30:327

    Article  Google Scholar 

  18. Kim WJ, Yoo JC, Hayhurst DT (2001) Microporous Mesoporous Mater 49:125

    Article  CAS  Google Scholar 

  19. Xia Y, Mokaya R (2004) Microporous Mesoporous Mater 68:1

    Article  CAS  Google Scholar 

  20. Ryoo R, Ko CH, Howe RF (1997) Chem Mater 9:1607

    Article  CAS  Google Scholar 

  21. Prokesova P, Mintova S, Cejika J, Bein T (2003) Microporous Mesoporous Mater 64:165

    Article  CAS  Google Scholar 

  22. Kao H-M, Wu H-M, Liao Y-W, Chiang AST (2005) Microporous Mesoporous Mater 86:256

    Article  CAS  Google Scholar 

  23. Sakthivel A, Huang S-J, Chen W-H, Lan Z-H, Chen K-H, Lin H-P, Mou C-Y, Liu S-B (2005) Adv Funct Mater 15:253

    Article  CAS  Google Scholar 

  24. Laha SC, Sakthivel A, Komura K, Huang S-J, Wu P-H, Liu S-B, Sasaki Y, Kobayashi M, Sugi S (2009) Chem Lett 38:548

    Article  CAS  Google Scholar 

  25. Vaudy F, Di Renzo F, Espian P, Fajula F (1997) Zeolite 19:253

    Article  Google Scholar 

  26. Barbosa VFF, MacKenzie KJD, Thaumaturgi C (2003) Mater Lett 57:1477

    Article  CAS  Google Scholar 

  27. Corma A, Fornes V, Navarro MT, Perez-Pariente J (1994) J Catal 148:569

    Article  CAS  Google Scholar 

  28. Ryoo R, Jun S, Kim JM, Kim MJ (1997) Chem Commun 22:2225

    Article  Google Scholar 

  29. Miyamoto Y, Katada N, Niwa M (2000) Microporous Mesoporous Mater 40:271

    Article  CAS  Google Scholar 

  30. Tatsumi T, Koyano KA, Tanaka Y, Nakata S (1997) Chem Lett 26:469

    Article  Google Scholar 

Download references

Acknowledgment

A part of this work has financially been supported by Grant-in-Aid for Scientific Research (B) 16310056, 19310060, and (C) 21510098, the Japan Society for the Promotion of Science (JSPS). C. Venkatesan and S. C. Laha are grateful to JSPS for their postdoctoral fellowships. The authors are also grateful to the Department of Research, Nagoya Industrial Science Research Institute for their continuing cooperation.

Author information

Authors and Affiliations

  1. Department of Materials Science and Technology, Faculty of Engineering, Gifu University, Gifu, 501-1193, Japan

    Kenichi Komura, Yuki Tsuchiya, Chithravel Venkatesan, Subhash Chandra Laha & Yoshihiro Sugi

  2. Nanostructure Research Laboratory, Japan Fine Ceramics Centre, Nagoya, 456-8587, Japan

    Yukichi Sasaki & Midori Kobayashi

Authors
  1. Kenichi Komura
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuki Tsuchiya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chithravel Venkatesan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Subhash Chandra Laha
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yukichi Sasaki
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Midori Kobayashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yoshihiro Sugi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kenichi Komura.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Komura, K., Tsuchiya, Y., Venkatesan, C. et al. Convenient Synthesis of Mesoporous Aluminosilicates by Using Pre-heated Sodium Aluminosilicate Gel. Top Catal 53, 529–534 (2010). https://doi.org/10.1007/s11244-010-9482-z

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-010-9482-z

Keywords

Search

Navigation