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Operando X-ray Absorption Spectroscopy Study of Pt/γ-Al2O3 During the Total Oxidation of C3H6

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Abstract

Operando X-ray absorption fine structure (XAFS) investigations were performed on Pt/γ-Al2O3 during the total oxidation of C3H6 in reducing and oxidizing atmospheres. Study of the Pt valance state and catalytic conversion behavior as a function of temperature revealed that both the creation of metallic Pt sites and the activation of adsorbed species on Pt are important for the functioning of the catalytic reaction at low temperature.

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References

  1. Topsøe H (2003) J Catal 216:155

    Article  Google Scholar 

  2. Weckhuysen BM (2003) Phys Chem Chem Phys 5:4351

    Article  CAS  Google Scholar 

  3. Banares MA (2005) Catal Today 100:71

    Article  CAS  Google Scholar 

  4. Bennici SM, Vogelaar BM, Nijhuis TA, Weckhuysen BM (2007) Angew Chem Int Ed 46:5412

    Article  CAS  Google Scholar 

  5. Nijhuis TA, Tinnemans SJ, Visser T, Weckhuysen B (2004) Chem Eng Sci 59:5487

    Article  CAS  Google Scholar 

  6. Demoulin O, Navez M, Gaigneaux EM, Ruiz P, Mamede A, Granger P, Payen E (2003) Phys Chem Chem Phys 5:4394

    Article  CAS  Google Scholar 

  7. Lesage T, Verrier C, Bazin P, Saussey J, Daturi M (2003) Phys Chem Chem Phys 5:4435

    Article  CAS  Google Scholar 

  8. Lesage T, Saussey J, Malo S, Hervieu M, Hedouin C, Blanchard G, Daturi M (2007) Appl Catal B Environ 72:166

    Article  CAS  Google Scholar 

  9. Meunier FC, Goguet A, Hardacre C, Burch R, Thompsett D (2007) J Catal 252:18

    Article  CAS  Google Scholar 

  10. Tibiletti D, Meunier FC, Goguet A, Reid D, Burch R, Boaro M, Vicario M, Trovarelli A (2006) J Catal 244:183

    Article  CAS  Google Scholar 

  11. Newton MA, Dent AJ, Fiddy SG, Jyoti B, Evans J (2007) Catal Today 126:64

    Article  CAS  Google Scholar 

  12. Mondelli C, Ferri D, Grunwaldt JD, Krumeich F, Mangold S, Psaro R, Baiker A (2007) J Catal 252:77

    Article  CAS  Google Scholar 

  13. Puurunen RL, Beheydt BG, Weckhuysen BM (2001) J Catal 204:253

    Article  CAS  Google Scholar 

  14. Puurunen RL, Weckhuysen BM (2002) J Catal 210:418

    Article  CAS  Google Scholar 

  15. Lamberti C, Bordiga S, Bonino F, Prestipino C, Berlier G, Capello L, D’Acapito F, Xamena FXLI, Zecchina A (2003) Phys Chem Chem Phys 5:4502

    Article  CAS  Google Scholar 

  16. Caravati M, Grunwaldt JD, Baiker A (2007) Catal Today 126:27

    Article  CAS  Google Scholar 

  17. Tada M, Murata S, Asakoka T, Hiroshima K, Okumura K, Tanida H, Uruga T, Nakanishi H, Matsumoto S, Inada Y, Nomura M, Iwasawa Y (2007) Angew Chem Int Ed 46:4310

    Article  CAS  Google Scholar 

  18. Grunwaldt JD, van Vegten N, Baiker A (2007) Chem Commun 4635

  19. Bruckner A (2003) Phys Chem Chem Phys 5:4461

    Article  Google Scholar 

  20. Hunger M, Wang W (2004) Chem Commun 584

  21. Hunger M, Horvath T (1995) J Chem Soc Chem Commun 1423

  22. Brückner A (2005) Chem Commun 1761

  23. Beale AM, van der Eerden AMJ, Kervinen K, Newton MA, Weckhuysen BM (2005) Chem Commun 3015

  24. Tinnemans SJ, Mesu JG, Kervinen K, Visser T, Nijhuis TA, Beale AM, Keller DE, van der Eerden AMJ, Weckhuysen BM (2006) Catal Today 113:3

    Article  CAS  Google Scholar 

  25. Brückner A, Kondratenko E (2006) Catal Today 113:16

    Article  Google Scholar 

  26. Bare SR, Yang N, Kelly SD, Mickelson GE, Modica FS (2007) Catal Today 126:18

    Article  CAS  Google Scholar 

  27. Ferrer S, Petroff Y (2002) Surf Sci 500:605

    Article  CAS  Google Scholar 

  28. Yamamoto T, Suzuki A, Nagai Y, Tanabe T, Dong F, Inada Y, Nomura M, Tada M, Iwasawa Y (2007) Angew Chem Int Ed 46:9253

    Article  CAS  Google Scholar 

  29. Okumura K, Kato K, Sanada T, Niwa M (2007) J Phys Chem C 111:14426

    Article  CAS  Google Scholar 

  30. Mansour AN, Cook JW, Sayers DE (1984) J Phys Chem A 88:2330

    CAS  Google Scholar 

  31. Yoshida H, Nonoyama S, Yazawa Y, Hattori T (2005) Phys Scr T 115:813

    Article  Google Scholar 

  32. Yu Yao Y-F (1984) J Catal 87:152

    Article  Google Scholar 

  33. Burnett DJ, Gabelnick AM, Marsh AL, Fischer DA, Gland JL (2004) Surf Sci 553:1

    Article  CAS  Google Scholar 

  34. Gabelnick AM, Capitano AT, Kane SM, Gland JL, Fischer DA (2000) J Am Chem Soc 122:143

    Article  CAS  Google Scholar 

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Acknowledgment

We gratefully thank Dr. Uruga, Dr. Tanida and Dr. Kato (Japan Synchrotron Research Institute) for their assistance in the XAFS experiments at Spring-8.

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Authors and Affiliations

  1. Toyota Central R&D Labs., Inc, Nagakute, Aichi-gun, Aichi, 480-1192, Japan

    Toshitaka Tanabe, Yasutaka Nagai, Kazuhiko Dohmae, Naoki Takahashi & Hirohumi Shinjoh

  2. TOYOTA Motor Corporation, Toyota, Aichi, 471-8572, Japan

    Nobuyuki Takagi

Authors
  1. Toshitaka Tanabe
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  2. Yasutaka Nagai
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  3. Kazuhiko Dohmae
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  4. Nobuyuki Takagi
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  5. Naoki Takahashi
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  6. Hirohumi Shinjoh
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Corresponding author

Correspondence to Toshitaka Tanabe.

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Tanabe, T., Nagai, Y., Dohmae, K. et al. Operando X-ray Absorption Spectroscopy Study of Pt/γ-Al2O3 During the Total Oxidation of C3H6 . Top Catal 52, 1433–1439 (2009). https://doi.org/10.1007/s11244-009-9319-9

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  • DOI: https://doi.org/10.1007/s11244-009-9319-9

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