Abstract
Supported NbN catalysts were prepared under a N2–H2 gas stream by the addition of Fe species to Nb/SiO2. The nitriding process was monitored by in situ XAFS measurements. Fe K-edge XAFS and Nb K-edge in situ XAFS measurements revealed that Fe species in close proximity to niobium oxide can effectively induce nitridation of the niobium oxide with the nitriding rate being dependent upon the dispersion of Fe species. It was concluded that the dispersed Fe species close to niobium effectively assisted the nitridation of niobium oxide into NbN. The nitriding degree can be expressed by the coordination number of Nb–N.
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Oyama ST (ed) (1996) In: The chemistry of transition metal carbides and nitrides. Blackie A&P, London, p 1
Volpe L, Boudart M (1986) J Phys Chem 90:4874
Ranhotra GS, Bell AT, Reimer JA (1987) J Catal 108:40
Schlatter JC, Oyama ST, Metcalfe JE III, Lambert JM Jr (1988) Ind Eng Chem Res 27:1648
Nagai M, Miyao T (1992) Catal Lett 15:105
Nagai M, Miyao T, Tuboi T (1993) Catal Lett 18:9
Mariadassou GD, Boudart M, Bugli G, Sayag C (1995) Catal Lett 31:411
Sajkowski DJ, Oyama ST (1996) Appl Catal A 134:339
Wu Z, Valiente AM, Ruiz AG, Ramos IR, Li C, Xin Q (2003) Phys Chem Chem Phys 5:1703
Mckay D, Hargreaves JSJ, Rico JL, Rivera JL, Sun XL (2008) J Solid State Chem 181:325
Troitskiy VN, Domashnev IA, Kurkin EN, Grebtsova OM, Berestenko VI, Balikhim IL, Gurov SV (2003) J Nanoparticle Res 5:521
Angelkort C, Lewalter H, Warbichler P, Hofer F, Bock W, Kolbesen BO (2001) Spectro Acta A 57:2077
Passoni LC, Siddiqui MRH, Steiner A, Kozhevnikov IV (2000) J Mol Catal A 153:103
Ichikuni N, Matsumoto H, Haneishi H, Bando KK, Shimazu S (2007) AIP Conf Proc 882:639
Kodama S, Ichikuni N, Bando KK, Hara T, Shimazu S (2008) Appl Catal A 343:25
Ichikuni N, Hachiya H, Bando KK, Shimazu S, Uematsu T (2005) Phys Scr T115:807
McKale AG, Veal BW, Paulikas AP, Chan SK, Knapp GS (1988) J Am Chem Soc 110:3763
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Wakai, Y., Hara, T., Bando, K.K. et al. Promotional Effect of Iron for the Nitridation of Niobium Oxide to Niobium Nitride. Top Catal 52, 1517–1524 (2009). https://doi.org/10.1007/s11244-009-9292-3
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DOI: https://doi.org/10.1007/s11244-009-9292-3