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Hydrogen Oxidation Catalyzed by Pt Supported on Carbon Nanofibers with Different Graphite Sheet Orientations

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Abstract

The kinetic study of hydrogen oxidation with or without the presence of CO has been used as a tool to study the relative oxygen and CO adsorption strength on Pt nanoparticles, which are important parameters for fuel cell catalysts. It was found that the activation energy, which is determined by the oxygen binding energy, is influenced by the CNF graphite sheet orientation, CNF oxygen groups and catalyst preparation method. A weaker bonding of oxygen was indicated for Pt nanoparticles supported on platelet compared to Pt on fishbone CNFs. Moreover, oxygen seemed to be more strongly bonded to Pt particles on CNFs prepared by deposition–precipitation compared to those prepared by incipient wetness impregnation and a metal-oxide colloid method. Enhanced CO-adsorption was indicated for Pt supported on carbon nanofibers with introduced oxygen groups.

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Acknowledgments

This work was supported by the Research Council of Norway, Grant No. 158516/S10 (NANOMAT). Heimir Magnusson, formerly working at NTNU, now at JEOL, is acknowledged for his help with the transmission electron microscopy experiments.

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Authors and Affiliations

  1. Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim, Norway

    Ingvar Kvande, De Chen, Tie-Jun Zhao & Magnus Rønning

  2. Department of Physics, Norwegian University of Science and Technology, Trondheim, Norway

    Inger Marie Skoe & John C. Walmsley

  3. Department of Synthesis and Properties, SINTEF Materials and Chemistry, Trondheim, 7491, Norway

    John C. Walmsley

Authors
  1. Ingvar Kvande
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  2. De Chen
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  3. Tie-Jun Zhao
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  4. Inger Marie Skoe
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  5. John C. Walmsley
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  6. Magnus Rønning
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Corresponding author

Correspondence to De Chen.

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Kvande, I., Chen, D., Zhao, TJ. et al. Hydrogen Oxidation Catalyzed by Pt Supported on Carbon Nanofibers with Different Graphite Sheet Orientations. Top Catal 52, 664–674 (2009). https://doi.org/10.1007/s11244-009-9218-0

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