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Applications of Amine-functionalized Mesoporous Silica in Fine Chemical Synthesis

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Abstract

SBA-15 silica containing homogeneously distributed amine-functional groups and of fiber or platelet morphology was prepared through a modified co-condensation method using P123 copolymer as template under acidic condition. Synthetic factors which led to well-ordered mesoporous materials with high loadings of various amine groups were discussed. The resultant mesoporous materials were efficient base catalysts in Knoevenagel and Claisen–Schmidt addition reactions. The activities over SBA-15 materials with different amino-functional groups are compared. Moreover, the advantage of ordered large mesopores of SBA-15 in catalyzing liquid phase reactions was demonstrated, and the reaction rate could be further increased when SBA-15 was with platelet morphology and short mesochannels.

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Acknowledgements

This work was supported by National Science Council and the Ministry of Education, Taiwan.

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Authors and Affiliations

  1. Department of Chemistry, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei, 10617, Taiwan

    Soofin Cheng, Xueguang Wang & Shih-Yuan Chen

  2. Department of Materials and Engineering, School of Materials Science and Engineering, Shanghai University, Shanghai, 200072, China

    Xueguang Wang

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  1. Soofin Cheng
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  2. Xueguang Wang
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Correspondence to Soofin Cheng.

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Dedicated to the 50th Anniversary of Catalysis Society of Japan.

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Cheng, S., Wang, X. & Chen, SY. Applications of Amine-functionalized Mesoporous Silica in Fine Chemical Synthesis. Top Catal 52, 681–687 (2009). https://doi.org/10.1007/s11244-009-9216-2

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