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Self-Metathesis of 1-Octene Using Alumina-Supported Re2O7 in Supercritical CO2

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Abstract

In this contribution we describe the use of heterogeneous catalysts for the liquid-phase self-metathesis of 1-octene in supercritical CO2. Our work aims at addressing the mass-transfer problems associated with such reaction systems. By coupling a heterogeneous supported Re2O7 catalyst with the use of scCO2, the self-metathesis of 1-octene takes place by and large much more rapidly than in traditional solvent media, and furthermore, by using scCO2 the overall efficiency and sustainability of the transformation can be improved.

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Acknowledgments

The Italian Ministry for University and Research is acknowledged for funding. AP thanks the Australian DEST for an Endeavour Research Fellowship and RSC for a Travel Grant.

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Authors and Affiliations

  1. Dipartimento di Scienze Ambientali, Università Ca’ Foscari, Dorsoduro, 2137–30123, Venezia, Italy

    Massimo Fabris, Alvise Perosa & Maurizio Selva

  2. Laboratory for Advanced Catalysis and Sustainability, School of Chemistry, University of Sydney, 2006, Sydney, NSW, Australia

    Cindy Aquino, Antony J. Ward & Thomas Maschmeyer

Authors
  1. Massimo Fabris
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  2. Cindy Aquino
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  3. Antony J. Ward
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  4. Alvise Perosa
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  5. Thomas Maschmeyer
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  6. Maurizio Selva
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Corresponding authors

Correspondence to Thomas Maschmeyer or Maurizio Selva.

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Fabris, M., Aquino, C., Ward, A.J. et al. Self-Metathesis of 1-Octene Using Alumina-Supported Re2O7 in Supercritical CO2 . Top Catal 52, 315–321 (2009). https://doi.org/10.1007/s11244-008-9154-4

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  • DOI: https://doi.org/10.1007/s11244-008-9154-4

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