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Chemicals from Biomass: Aerobic Oxidation of 5-Hydroxymethyl-2-Furaldehyde into Diformylfurane Catalyzed by Immobilized Vanadyl-Pyridine Complexes on Polymeric and Organofunctionalized Mesoporous Supports

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Abstract

Diformylfurane (DFF) has been obtained by aerobic oxidation of 5-hydroxymethyl-2-furaldehyde (HMF) with homogeneous pyridine-vanadyl complexes in homogeneous phase, with Cu and V in poly(4-vinylpyridine) crosslinked with 33% divinylbenzene (PVP) and supported on organofunctionalized SBA-15 mesoporous materials. Detailed spectroscopic characterization of the materials is provided. Catalytic results show that pyridine-vanadyl complexes supported on SBA-15 are less active than when in the polymeric form. The nature of the catalyst surface and solvent plays a key role on the catalytic behaviour.

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Acknowledgments

The authors wish to acknowledge the Spanish Ministry of Education and Science for the financial support in the project MAT 2006-14274-C02-01. O. C. is grateful to the Spanish Council for Scientific Research (CSIC) for a PhD scholarship.

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Authors and Affiliations

  1. Instituto de Tecnología Química (UPV-CSIC), Universitat Politècnica de València, Avda dels Tarongers s/n, 46022, Valencia, Spain

    Onofre Casanova Navarro , Avelino Corma Canós & Sara Iborra Chornet

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  1. Onofre Casanova Navarro
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  2. Avelino Corma Canós
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  3. Sara Iborra Chornet
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Correspondence to Avelino Corma Canós.

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Navarro , O.C., Canós, A.C. & Chornet, S.I. Chemicals from Biomass: Aerobic Oxidation of 5-Hydroxymethyl-2-Furaldehyde into Diformylfurane Catalyzed by Immobilized Vanadyl-Pyridine Complexes on Polymeric and Organofunctionalized Mesoporous Supports. Top Catal 52, 304–314 (2009). https://doi.org/10.1007/s11244-008-9153-5

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