Skip to main content
SpringerLink
Log in

Effect of Method on Monolayer Assembly of Zeolite Microcrystals on Glass with Molecular Linkages

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

The effect of method on the mode of reaction progress and the characteristic properties of the assembled monolayers were investigated during the monolayer assembly of bare zeolite microcrystals onto 3-chloropropyl-tethering glass plates. The tested methods were reflux, reflux with stirring, sonication, and sonication with stacking between the glass plates. The results revealed that the type of method sensitively affects the profiles of the coverage and the binding strength with time and that the monolayer assembly consists of four key steps: dispersion of microcrystals into the solution, attachment of microcrystals onto the substrate, migration of the randomly attached crystals leading to close packing between the microcrystals, and replacement of the substrate-bound microcrystals with those in solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Scheme 1
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16

Similar content being viewed by others

References

  1. Yoon KB (2007) Acc Chem Res 40:29–40

    Article  CAS  Google Scholar 

  2. Yoon KB (2006) Bull Kor Chem Soc 27:17

    Article  CAS  Google Scholar 

  3. Lee JA, Meng L, Norris DJ, Scriven LE, Tsapatsis M (2006) Langmuir 22:5217–5219

    Article  CAS  Google Scholar 

  4. Lai ZP, Bonilla G, Diaz I, Nery JG, Sujaoti K, Amat MA, Kokkoli E, Terasaki O, Thompson RW, Tsapatsis M, Vlachos DG (2003) Science 300:456–460

    CAS  Google Scholar 

  5. Mabande GTP, Ghosh S, Lai ZP, Schwieger W, Tsapatsis M (2005) Ind Eng Chem Res 44:9086–9095

    Article  CAS  Google Scholar 

  6. Li S, Li Z, Bozhilov KN, Chen Z, Yan Y (2004) J Am Chem Soc 126:10732–10737

    Article  CAS  Google Scholar 

  7. Wang Z, Mirta A, Wang H, Huang L, Yan Y (2001) Adv Mater 13:1463–1466

    Article  CAS  Google Scholar 

  8. Wang Z, Mirta A, Wang H, Huang L, Yan Y (2001) Adv Mater 13:746–749

    Article  CAS  Google Scholar 

  9. Laine P, Seifert R, Giovanoli R, Calzaferri G (1997) New J Chem 21:453–460

    CAS  Google Scholar 

  10. Calzaferri G, Bossart O, Bruhwiler D, Huber S, Leiggener C, van Veen MK, Ruiz AZ (2006) C R Chimie 9:214–225

    CAS  Google Scholar 

  11. Ruiz AZ, Li H, Calzaferri G (2006) Angew Chem Int Ed 45:5282–5287

    Article  CAS  Google Scholar 

  12. Kim HS, Lee SM, Ha K, Jung C, Lee Y-J, Chun YS, Kim D, Rhee BK, Yoon KB (2004) J Am Chem Soc 126:673–682

    Article  CAS  Google Scholar 

  13. Kim HS, Lee MH, Jeong NC, Lee SM, Rhee BK, Yoon KB (2006) J Am Chem Soc 128:15070–15071

    Article  CAS  Google Scholar 

  14. Kim HS, Sohn KW, Jeon Y, Min H, Kim D, Yoon KB (2007) Adv Mater 19:260–263

    Article  CAS  Google Scholar 

  15. Kim HS, Pham TT, Yoon KB (2008) J Am Chem Soc 130:2134–2135

    Article  CAS  Google Scholar 

  16. Lee JS, Lim H, Ha K, Cheong H, Yoon KB (2006) Angew Chem 45:288–5292

    Google Scholar 

  17. Ozin GA, Kuperman A, Stein A (1989) Angew Chem Int Ed Engl 28:359–376

    Article  Google Scholar 

  18. Davis ME (2002) Nature 417:813–821

    Article  CAS  Google Scholar 

  19. Ozin GA, Stein A, Stucky GD, Godber JP (1990) J Inclusion Phenom 6:379–393

    Google Scholar 

  20. Borja M, Dutta PK (1993) Nature 362:43–45

    Article  CAS  Google Scholar 

  21. Sykora M, Kincaid JR (1997) Nature 387:162–164

    Article  CAS  Google Scholar 

  22. Kim YI, Keller SW, Krueger JS, Yonemoto EH, Saupe GB, Mallouk TE (1997) J Phys Chem B 101:2491–2500

    Article  CAS  Google Scholar 

  23. Rolison DR, Bessel CA (2000) Acc Chem Res 33:737–744

    Article  CAS  Google Scholar 

  24. Kulak A, Lee Y-J, Park YS, Yoon KB (2000) Angew Chem Int Ed 39:950–953

    Article  CAS  Google Scholar 

  25. Choi SY, Lee Y-J, Park YS, Ha K, Yoon KB (2000) J Am Chem Soc 122:5201–5209

    Article  CAS  Google Scholar 

  26. Kulak A, Park YS, Lee Y-J, Chun YS, Ha K, Yoon KB (2000) J Am Chem Soc 122:9308–9309

    Article  CAS  Google Scholar 

  27. Lee JS, Ha K, Lee Y-J, Yoon KB (2005) Adv Mater 17:837–841

    Article  CAS  Google Scholar 

  28. Lee JS, Kim JH, Lee YJ, Jeong NC, Yoon KB (2007) Angew Chem Int Ed 46:3087–3090

    Article  CAS  Google Scholar 

  29. Ha K, Lee Y-J, Lee HJ, Yoon KB (2000) Adv Mater 12:1114–1117

    Article  CAS  Google Scholar 

  30. Mason TJ, Lorimer JP, Mistry BP (1985) Tetrahedron 41:5201–5204

    Article  CAS  Google Scholar 

  31. Mason TJ, Lorimer JP (1988) In: Kemp, TJ (ed) Sonochemistry: theory, applications and uses of ultrasound in chemistry. Ellis Horwood, Chichester, Chapter 2, pp 17–63

  32. Mason, TJ (1991) In: Mellor J (ed) Practical Sonochemistry: user’s guide to applications in chemistry and chemical engineering. Ellis Horwood, Chichester, Chapter 1, pp 17–51

  33. Grubert G, Stockenhuber M, Tkachenko OP, Wark M (2002) Chem Mater 14:2458–2466

    Article  CAS  Google Scholar 

  34. Calzaferri G, Pauchard M, Maas H, Huber S, Khatyr A, Schaafsma T (2002) J Mater Chem 12:1–13

    Article  CAS  Google Scholar 

  35. Vietze U, Krauß O, Laeri F, Ihlein G, Schüth F, Limburg B, Abraham M (1998) Phys Rev Lett 81:4628–4631

    Article  CAS  Google Scholar 

Download references

Acknowledgment

We thank the Ministry of Science and Technology of the Korean Government and Sogang University for supporting this work through the Acceleration Research and Internal University Research programs.

Author information

Authors and Affiliations

  1. Center for Microcrystal Assembly, Department of Chemistry, Sogang University, Seoul, 121-742, South Korea

    Jin Seok Lee, Kwang Ha, Yun-Jo Lee & Kyung Byung Yoon

Authors
  1. Jin Seok Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kwang Ha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yun-Jo Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kyung Byung Yoon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kyung Byung Yoon.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lee, J.S., Ha, K., Lee, YJ. et al. Effect of Method on Monolayer Assembly of Zeolite Microcrystals on Glass with Molecular Linkages. Top Catal 52, 119–139 (2009). https://doi.org/10.1007/s11244-008-9148-2

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-008-9148-2

Keywords

Search

Navigation