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Ethylene combustion on unsupported and supported Pd: a comparative study

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Ethylene combustion is studied at elevated pressures on Pd(100) and compared with supported Pd catalysts. Specific rates of CO2 formation were determined on Pd(100), 1 wt% (dPd = 2.5 nm) and 5 wt% (dPd = 4.2 nm) Pd/SiO2 catalysts as a function of the O2/C2H4 ratio over the temperature range 428–473 K. Reaction rates and apparent activation energies on these catalysts are particle size and reactant ratio dependent. The surface carbon concentration on Pd(100) depends on the ratio of the reactants and decreases with increasing O2 pressure. The combustion kinetics is related to the corresponding surface carbon coverage; the highest reaction rate was achieved for relatively low coverage of surface carbon.

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References

  1. C. Pliangos I.V. Yentekakis V.G. Papadakis C.G. Vayenas X.E. Verykios (1997) Appl. Catal. B: Environmental 14 161 Occurrence Handle10.1016/S0926-3373(97)00020-9 Occurrence Handle1:CAS:528:DyaK2sXns1eqt7g%3D

    Article  CAS  Google Scholar 

  2. J.M.A. Harmsen J.H.B. Hoebink J.C. Schouten (2000) Ind. Eng. Chem. Res. 39 599 Occurrence Handle10.1021/ie990614g Occurrence Handle1:CAS:528:DC%2BD3cXovF2lsg%3D%3D

    Article  CAS  Google Scholar 

  3. J.T. Kummer (1986) J. Phys. Chem. 90 4747 Occurrence Handle10.1021/j100411a008 Occurrence Handle1:CAS:528:DyaL28Xltlyrsbs%3D

    Article  CAS  Google Scholar 

  4. J. Barbier SuffixJr. D. Duprez (1994) Appl. Catal. B: Environmental 4 105 Occurrence Handle10.1016/0926-3373(94)80046-4 Occurrence Handle1:CAS:528:DyaK2cXmtFWls7Y%3D

    Article  CAS  Google Scholar 

  5. R.E. Kenson M. Lapkin (1970) J. Phys. Chem. 74 1493 Occurrence Handle10.1021/j100702a017 Occurrence Handle1:CAS:528:DyaE3cXht1Srs78%3D

    Article  CAS  Google Scholar 

  6. C.G. Vayenas B. Lee J. Michaels (1980) J. Catal. 66 36 Occurrence Handle10.1016/0021-9517(80)90005-6 Occurrence Handle1:CAS:528:DyaL3MXivFykug%3D%3D

    Article  CAS  Google Scholar 

  7. T.C. Bissot, US Patent, 4048096

  8. B. Samanos P. Boutry R. Montarnal (1971) J. Catal. 23 19 Occurrence Handle10.1016/0021-9517(71)90019-4 Occurrence Handle1:CAS:528:DyaE3MXkvVSrs7Y%3D

    Article  CAS  Google Scholar 

  9. E.A. Crathorne D. MacGowan S.R. Morris A.P. Rawlinson (1994) J. Catal. 149 54 Occurrence Handle10.1006/jcat.1994.1294

    Article  Google Scholar 

  10. S. Nakamura T. Yasui (1970) J. Catal. 17 366 Occurrence Handle10.1016/0021-9517(70)90113-2 Occurrence Handle1:CAS:528:DyaE3cXktVehsLs%3D

    Article  CAS  Google Scholar 

  11. Y.-F. Han D. Kumar D.W. Goodman (2005) J. Catal. 230 353 Occurrence Handle10.1016/j.jcat.2004.12.018 Occurrence Handle1:CAS:528:DC%2BD2MXhvVSksbg%3D

    Article  CAS  Google Scholar 

  12. Y.-F. Han D. Kumar C. Sivadinarayana D.W. Goodman (2004) J. Catal. 224 60 Occurrence Handle10.1016/j.jcat.2004.02.028 Occurrence Handle1:CAS:528:DC%2BD2cXjsVejt7k%3D

    Article  CAS  Google Scholar 

  13. X.-C. Guo R.J. Madix (1995) J. Am. Chem. Soc. 117 5523 Occurrence Handle10.1021/ja00125a013 Occurrence Handle1:CAS:528:DyaK2MXls1yqsrk%3D

    Article  CAS  Google Scholar 

  14. D.W. Goodman (1982) J. Vac. Sci. Technol. 20 522 Occurrence Handle10.1116/1.571422 Occurrence Handle1:CAS:528:DyaL38XhvVOqsr0%3D

    Article  CAS  Google Scholar 

  15. P.L.J. Gunter J.W. Niemantsverdriet F.H. Ribeiro G.A. Somorjai (1997) Catal. Rev. Sci. Eng. 39 77 Occurrence Handle10.1080/01614949708006469 Occurrence Handle1:CAS:528:DyaK2sXjtFGrsrw%3D

    Article  CAS  Google Scholar 

  16. D.W. Goodman (1995) Chem. Rev. 95 523 Occurrence Handle10.1021/cr00035a004 Occurrence Handle1:CAS:528:DyaK2MXltlyktbw%3D

    Article  CAS  Google Scholar 

  17. D.A. Shirley (1972) Phys. Rev. B 5 4700

    Google Scholar 

  18. D. Bürgler G. Tarrach T. Schaub R. Wiesendanger H.-J. Güntherodt (1992) Phys. Rev. B 47 9963 Occurrence Handle10.1103/PhysRevB.47.9963

    Article  Google Scholar 

  19. U. Ackelid L. Olsson L.-G. Petersson (1996) J. Cat. 161 143 Occurrence Handle10.1006/jcat.1996.0171 Occurrence Handle1:CAS:528:DyaK28XksFGjtbY%3D

    Article  CAS  Google Scholar 

  20. M. Valden X. Lai D.W. Goodman (1998) Science 281 1647 Occurrence Handle10.1126/science.281.5383.1647 Occurrence Handle1:CAS:528:DyaK1cXmtVSqu7w%3D

    Article  CAS  Google Scholar 

  21. D. Stacchiola W.T. Tysoe (2002) Surf. Sci. 513 L431 Occurrence Handle10.1016/S0039-6028(02)01857-5 Occurrence Handle1:CAS:528:DC%2BD38Xltlens7k%3D

    Article  CAS  Google Scholar 

  22. J.A. Gates L.L. Kesmodel (1982) Surf. Sci. 120 L461 Occurrence Handle10.1016/0039-6028(82)90141-8 Occurrence Handle1:CAS:528:DyaL38Xls12msbc%3D

    Article  CAS  Google Scholar 

  23. P. Cremer X. Su Y. Shen G.A. Somorjai (1996) Catal. Lett. 40 43 Occurrence Handle10.1007/BF00815274

    Article  Google Scholar 

  24. S. Shaikhutdinov M. Heemeier M. Bäumer T. Lear D. Lennon R.J. Oldman S.D. Jackson H.-J. Freund (2001) J. Catal. 200 330 Occurrence Handle10.1006/jcat.2001.3212 Occurrence Handle1:CAS:528:DC%2BD3MXktVKlsb0%3D

    Article  CAS  Google Scholar 

  25. E.M. Stuve R.J. Madix (1985) Surf. Sci. 160 293 Occurrence Handle10.1016/0039-6028(85)91043-X Occurrence Handle1:CAS:528:DyaL2MXlt12rsr8%3D

    Article  CAS  Google Scholar 

  26. E.M. Stuve R.J. Madix C.R. Brundle (1985) Surf. Sci. 152/153 532 Occurrence Handle10.1016/0039-6028(85)90185-2

    Article  Google Scholar 

  27. J.-F. Jia K. Wu S.-H. Lu R.-G. Zhao X.-M. Wei S.-C. Wu D.-Z. Wang (1995) Surf. Sci. 338 69 Occurrence Handle10.1016/0039-6028(95)00531-5 Occurrence Handle1:CAS:528:DyaK2MXnvFWmu7k%3D

    Article  CAS  Google Scholar 

  28. P.A.P. Nascente M.A. Hov ParticleVan G.A. Somorjai (1991) Surf. Sci. 253 167 Occurrence Handle10.1016/0039-6028(91)90590-O Occurrence Handle1:CAS:528:DyaK3MXlsVeht7c%3D

    Article  CAS  Google Scholar 

  29. M. Bowker C. Morgan N. Perkins R. Holroyd E. Fourre F. Grillo A. MacDowall (2005) J. Phys. Chem. B 109 2377 Occurrence Handle10.1021/jp0402232 Occurrence Handle1:CAS:528:DC%2BD2cXms1Cgsbw%3D

    Article  CAS  Google Scholar 

  30. E.M. Stuve R.J. Madix C.R. Brundle (1984) Surf. Sci. 146 155 Occurrence Handle10.1016/0039-6028(84)90235-8 Occurrence Handle1:CAS:528:DyaL2cXmtFOit7o%3D

    Article  CAS  Google Scholar 

  31. Y.-F. Han D. Kumar C. Sivadinarayana A. Clearfield D.W. Goodman (2004) Catal. Lett. 94 131 Occurrence Handle10.1023/B:CATL.0000020537.33875.46 Occurrence Handle1:CAS:528:DC%2BD2cXitlWrsLo%3D

    Article  CAS  Google Scholar 

  32. M. Bowker C. Morgan (2004) Catal. Lett. 98 67 Occurrence Handle10.1007/s10562-004-6448-4 Occurrence Handle1:CAS:528:DC%2BD2cXovFams78%3D

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX, 77843-3012, USA

    D. Kumar, Y.-F. Han & D. W. Goodman

  2. Institute of Chemical and Engineering Sciences, Singapore, 627833, Singapore

    Y.-F. Han

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  1. D. Kumar
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  2. Y.-F. Han
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  3. D. W. Goodman
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Correspondence to D. W. Goodman.

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Kumar, D., Han, YF. & Goodman, D.W. Ethylene combustion on unsupported and supported Pd: a comparative study. Top Catal 46, 169–174 (2007). https://doi.org/10.1007/s11244-007-0327-3

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