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A new [SiMo12O40]4−-based metal organic framework: synthesis, structure, photo-/electro-catalytic and absorption properties

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Abstract

The water pollution problems caused by organic dyes, inorganic ions and other pollutants are becoming more and more serious, and the removal of pollutants from wastewater is still a challenge. A polyoxometalate-based metal organic framework [Pr4(bpdc)4(H2O)10]·SiMo12O40·3H2O (1) (H2bpdc = 2,2′-bipyridine-6,6′-dicarboxylic acid) was synthesized for multi-functional treatment of pollutants in water. Structural analysis revealed that Keggin-type polyanions are sandwiched between adjacent lanthanide-organic layers. Electrochemical and dye removal experiments showed that compound 1 can not only reduce NO2− and BrO3− pollutants in water by electrocatalytic oxidation, but also photocatalytically degrade and adsorb cationic organic dye pollutants in water, and even adsorb cationic organic dyes from mixed dyes solution. It has been proved that compound 1 is a multifunctional water treatment agent.

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Acknowledgements

We are thankful for the financial support provided by the National Natural Science Foundation of China (No. 21902058, No. 22071080 and No. 222060555), the Natural Science Foundation of Jilin Province (No. YDZJ202101ZYTS175, YDZJ202101ZYTS096, YDZJ202201ZYTS360 and 20220101091JC), the Scientific Research Fund of Education Department of Jilin Province (No. JJKH20220234KJ) and acknowledge the assistance of JLICT Center of Characterization and Analysis.

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Authors and Affiliations

  1. Jilin Institute of Chemical Technology, Jilin City, 132022, Jilin, People’s Republic of China

    Jia-Qi Geng, Lu Yang, Xue Jiang, Lu-Kai Huang, Xiao-Shu Qu, Yan-Yan Yang, Hua Jin, Xue-Mei Li & Xiao-Yang Yu

  2. Petrochina Jilin Petrochemical Company Research Institute, Jilin City, 132022, Jilin, People’s Republic of China

    Yang Lu

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  1. Jia-Qi Geng
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Contributions

Jia-Qi Geng and Xiao-Yang Yu wrote the main manuscript text and prepared all the figures. Yang Lu did the photocatalytic experiments. Lu Yang, Xue Jiang and Lu-Kai Huang did the synthesis experiments. Xiao-Shu Qu and Yan-Yan Yang did the electrochemical experiments. Hua Jin and Xue-Mei Li did the absorption experiments. All authors reviewed the manuscript.

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Correspondence to Xiao-Yang Yu.

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Geng, JQ., Lu, Y., Yang, L. et al. A new [SiMo12O40]4−-based metal organic framework: synthesis, structure, photo-/electro-catalytic and absorption properties. Transit Met Chem (2024). https://doi.org/10.1007/s11243-024-00585-8

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