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Synthesis, characterization and crystallographic determination of symmetrical Schiff bases and their Zn(II) metal complexes

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Abstract

Two new tetradentate symmetrical Schiff bases derived from 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl or its dibromo substituted analog and 3,5-diiodosalicylaldehyde were synthesized. The reactions of these Schiff bases with zinc acetate generated the corresponding Zn(II)-complexes in which the zinc atom is bonded through the two azoimine nitrogen atoms in addition to the two oxygen atoms of the deprotonated hydroxyl groups. The Schiff bases and their Zn(II) complexes were characterized using UV-Vis, 1H- and 13C-NMR, IR spectroscopy and elemental analysis. The structures of the two Schiff bases as well as the two zinc(II) complexes were further approved by single crystal X-ray analysis.

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References

  1. Iacopetta D, Ceramella J, Catalano A, Mariconda A, Giuzio F, Saturnino C, Longo P, Sinicropi MS (2023) Inorganics 11:320

    Article  CAS  Google Scholar 

  2. Juyal VK, Pathak A, Panwar M, Thakuri SC, Prakash O, Agrwal A, Nand V (2023) J Organomet Chem 999:122825

    Article  CAS  Google Scholar 

  3. Ashraf T, Ali B, Qayyum H, Haroone MS, Shabbir G (2023) Inorg Chem Comm 150:110449

    Article  CAS  Google Scholar 

  4. Boulechfar C, Ferkous H, Delimi A, Djedouani A, Abdesalem K, Boublia A, Darwish AS, Lemaoui T, Verma R, Benguerba Y (2023) Inorg Chem Comm 150:110451

    Article  CAS  Google Scholar 

  5. Ejiah FN, Rofiu MO, Oloba-Whenu OA, Fasina TM (2023) Mater Adv 4:2308–2321

    Article  CAS  Google Scholar 

  6. Sandhu Q-U-A, Pervaiz M, Majid A, Younas U, Saeed Z, Ashraf A, Rashad R, Khan M, Ullah S, Ali F, Jelani S (2023) J Coord Chem 76:1094–1118

  7. Parvarinezhad S, Salehi M, Kubicki M, Malekshah RE (2022) J Mol Struct 1260:132780

    Article  CAS  Google Scholar 

  8. Roozbahani P, Salehi M, Malekshah RE, Kubicki M (2019) Inorg Chim Acta 496:119022

    Article  CAS  Google Scholar 

  9. Boulechfar C, Ferkous H, Delimi A, Berredjem M, Kahlouche A, Madaci A, Djellali S, Boufas S, Djedouani A, Errachid A, Khan AA, Boublia A, Lemaoui T, Benguerba Y (2023) J Mol Liquid 378:121637

    Article  CAS  Google Scholar 

  10. Afshari F, Ghomi ER, Dinari M, Ramakrishna S (2023) ChemSelect 8:e202203231

    CAS  Google Scholar 

  11. Ghasemi S, Andami Z (2017) ChemSelect 2:5864–5870

    CAS  Google Scholar 

  12. Tian Y, Wang K, Zhang H, Wu X, Zhong C (2022) Tetrahedron 113:132756

    Article  CAS  Google Scholar 

  13. Gautama C, Srivastava D, Kociok-Köhn G, Gosavic SW, Sharmaa VK, Chauhan R, Late DJ, Kumar A, Muddassir M (2023) RSC Adv 13:9046–9054

    Article  ADS  Google Scholar 

  14. Janjua UU, Pervaiz M, Ali F, Saleem A, Ashraf A, Younas U, Iqbal M (2023) Inorg Chem Comm 157:111233

    Article  CAS  Google Scholar 

  15. Roozbahani P, Malekshah RE, Salehi M, Parvarinezhad S, Kubicki M (2023) Appl Organomet Chem 37:e7254

    Article  CAS  Google Scholar 

  16. Parvarinezhad S, Salehi M, Kubicki M, Malekshah RE (2023) Appl Organomet Chem 36:e6836

    Article  Google Scholar 

  17. Yang Y-S, Ma S-S, Zhang Y-P, Ru J-X, Liu X-Y, Guo H-C (2018) Spectrochim Acta Mol Biomol Spectrosc 15:202–208

    Article  ADS  Google Scholar 

  18. Plitt P, Pritzkowa H, Krämer R (2004) Dalton Trans 2314–2320

  19. Karakayaa C, Dedeb B, Cicek E (2016) Acta Phys Pol 129:208–212

    Article  ADS  Google Scholar 

  20. Nagalakshmi V, Sathya M, Premkumar M, Kaleeswaran D, Venkatachalam G, Balasubramani K (2020) J Organom Chem 914:121220

    Article  CAS  Google Scholar 

  21. Ababneh TS, Al-Shboul TM, Jazzazi TM, Alomari MI, Görls H, Westerhausen M (2020) Trans Met Chem 45:435–442

    Article  CAS  Google Scholar 

  22. Al-Ebaisat HS, Ababneh TS, Al-Shboul TM, Jazzazi TM (2015) J Pure App Chem Res 5:125–130

    Article  Google Scholar 

  23. Jazzazi TM, Ababneh TS, Abboushi EK (2019) Jord J Chem 14:81–87

    CAS  Google Scholar 

  24. Al-Shboul TM, Ziemann S, Görls H, Krieck S, Westerhausen M (2019) Z Anorg Allg Chem 645:292–300

    Article  CAS  Google Scholar 

  25. Al-Shboul TM, Ziemann S, Görls H, Jazzazi TM, Krieck S, Westerhausen M (2018) Eur J Inorg Chem 14:1563–1570

    Article  Google Scholar 

  26. Al-Shboul TMA, El-khateeb M, Obeidat ZH, Ababneh TS, Al-Tarawneh SS, Al Zoubi MS, Alshaer W, Abu Seni A, Qasem T, Moriyama H, Yoshida Y, Kitagawa H, Jazzazi TMA (2022) Inorganics 10:112

    Article  CAS  Google Scholar 

  27. Ababneh TS, El-khateeb M, Tanash AK, Al-Shboul TMA, Shammout MJ, Jazzazi TMA, Alomari M, Daoud S, Talib W (2021) Pol J Chem Tech 23:7–15

    Article  CAS  Google Scholar 

  28. Daoud S, Thiab S, Jazzazi TMA, Al-Shboul TMA, Ullah S (2022) Acta Pharm 72:449–458

    Article  CAS  PubMed  Google Scholar 

  29. Petzold H, Alrawashdeh AI, Heider S, Haufe L, Rüffer T (2013) Eur J Inorg Chem 27:4858–4866

    Article  Google Scholar 

  30. Sheldrick GM (2014) SHELXS-2014, Program for Structure Solution; University of Göttingen: Göttingen, Germany

  31. Sheldrick GM (2014) SHELXL-2014, Program for Structure Refinement; University of Göttingen: Göttingen, Germany

  32. Shakir M, Hanif S, Sherwani MS, Mohammad O, Al-Resayes SI (2015) J Mol Struc 1092:143–158

    Article  ADS  CAS  Google Scholar 

  33. Gusev AN, Kiskin MA, Braga EV, Ktyukova MA, Baryshinkov GV, Karaush-Karmazin NN, Minaeva VA, Minaev BF, Ivaniuk K, Stakhira P, Ågren H, Linert W (2021) ACS Appl Electron Mater 3:3436–3444

    Article  CAS  Google Scholar 

  34. Hylland KY, Øien-Ødegaard S, Heyn RH, Tilest M (2020) Eur J Inorg Chem 15:3627–3643

    Article  Google Scholar 

  35. Basak T, Frontera A, Chattopadhyah S (2021) RSC Adv 11:30148–30155

    Article  ADS  CAS  PubMed  PubMed Central  Google Scholar 

Download references

Funding

We highly appreciate the generous financial support of the project 24/2023 by the Scientific Research Deanship at Yarmouk University (Irbid, Jordan).

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Authors and Affiliations

  1. Department of Chemistry, Yarmouk University, Irbid, 21163, Jordan

    Taghreed M. A. Jazzazi

  2. Department of Scientific Service Courses, Yarmouk University, Irbid, 21163, Jordan

    Tareq M. A. Al-Shboul

  3. Chemistry Department, Jordan University of Science and Technology, Irbid, 22110, Jordan

    Mohammad El-khateeb

  4. Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa- Oiwakecho, Sakyo-ku, Kyoto, 606-8502, Japan

    Hayato Moriyama, Yukihiro Yoshida & Hiroshi Kitagawa

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  1. Taghreed M. A. Jazzazi
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  2. Tareq M. A. Al-Shboul
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  4. Hayato Moriyama
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  5. Yukihiro Yoshida
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Contributions

TMJ and TMS conceptualization, supervision, experimental work, data collection, writing experimental part, review. ME writing the manuscript, collecting ideas, supervisor, HM X-ray structure measurements, writing experimental X-ray part. YY proof reading and x-ray discussion. HK supervision and revision.

Corresponding author

Correspondence to Mohammad El-khateeb.

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Jazzazi, T.M., Al-Shboul, T.M., El-khateeb, M. et al. Synthesis, characterization and crystallographic determination of symmetrical Schiff bases and their Zn(II) metal complexes. Transit Met Chem (2024). https://doi.org/10.1007/s11243-024-00578-7

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  • DOI: https://doi.org/10.1007/s11243-024-00578-7

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