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Synthesis, characterization of CdII-based complexes for efficient detection of copper(II) ions and antibiotics

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Abstract

In this work, two compounds, namely [Cd2(HL)(4,4′-bpy)(H2O)]n (1), [Cd2(HL)(bpa)(H2O)·2H2O]n (2) (2,3-bis(3,5-dicarboxylphenxoy)benzoic acid (H5L), 4,4′-bipyridine (4,4'-bpy) and 1,2-bi(4-pyridyl)ethane (bpa)), have been synthesized. Complex 1 showed three-dimensional metal–organic framework, which was assembled by carboxylic groups and one type of 4,4′-bpy ligand to layer structure, and further extended by the other type of 4,4′-bpy ligands, while complex 2 displayed 3D metal–organic framework with bpa hanging inside the hole. Fluorescence detection experiment showed that compound 1 can detect nitrofurazone, sulfachlopyridazine and sulfathiazole. In addition, compounds 1 and 2 can be served as luminescent probes for sensing Cu2+ ion.

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Acknowledgements

We gratefully acknowledge financial support by the National Natural Science Foundation of China (No. U1904199), Science Foundation for Excellent Youth of Henan Province (212300410064), the Program for Science and Technology Innovation Talents at the University of Henan Province (22HASTIT007), and Nanyang Normal University.

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Authors and Affiliations

  1. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Yi-Yang Zhao, Shan-Shan Liu, Ran Li, Ye Zhou & Bo Li

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  2. Shan-Shan Liu
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  4. Ye Zhou
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Contributions

BL conceived the idea and designed the research. YZ, SL RL and YZ synthesized and characterized the materials; all authors analyzed data and wrote the article. All authors reviewed the manuscript.

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Correspondence to Bo Li.

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Zhao, YY., Liu, SS., Li, R. et al. Synthesis, characterization of CdII-based complexes for efficient detection of copper(II) ions and antibiotics. Transit Met Chem 48, 135–142 (2023). https://doi.org/10.1007/s11243-023-00530-1

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  • DOI: https://doi.org/10.1007/s11243-023-00530-1

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