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C3-symmetric tripalladium(II) complex for catalysis via geometrical coincident interaction with C3-symmetric substrate

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Abstract

Reaction of cis-protected [(Me4en)Pd(SO4)] with the newly designed C3-symmetric Ba3L anionic ligand produces a stable trinuclear [(Me4enPd)3L] in a cis-O,O′ mode. A characteristic structural feature is that [(Me4enPd)3L] consists of a total of 10 rings with one 6-membered central benzene ring, three 5-membered rings (PdN2C2), three 6-membered rings (PdO2C3), and three 7-membered rings. This tripalladium(II) complex shows significant multi-center catalytic efficiency in the Heck reaction with the appropriate C3-symmetric trifunctional substrate via geometrical coincident interaction between the substrate and the catalyst. A theoretical calculation of the geometrical intermolecular interaction-behavior between the catalyst ([(Me4enPd)3L]) and the substrate (1,3,5-tris(4-iodophenyl)benzene) in N,N-dimethylformamide solution was carried out.

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Acknowledgements

This work was supported by National Research Foundation of Korea (NRF) grants funded by the Korean Government [MEST] (2021R1A2C2005105 and 2016R1A5A1009405) and BK21 FOUR Program by Pusan National University Research Grant (2020).

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  1. Department of Chemistry, Pusan National University, Busan, 46241, Republic of Korea

    Dongwon Kim, Jyoti Ramesh Jadhav, Junmyeong Park & Ok-Sang Jung

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DK contributed to investigation, conceptualization, and formal analysis. JRJ and JP contributed to investigation and methodology. OSJ contributed to funding acquisition, conceptualization, data curation, project administration, supervision, validation, and writing original draft.

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Correspondence to Ok-Sang Jung.

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Kim, D., Jadhav, J.R., Park, J. et al. C3-symmetric tripalladium(II) complex for catalysis via geometrical coincident interaction with C3-symmetric substrate. Transit Met Chem 48, 3–9 (2023). https://doi.org/10.1007/s11243-022-00519-2

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