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Manganese(II)-based coordination polymer as a bi-responsive luminescent sensor for highly selective detection of picric acid and CrO42− ion

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Abstract

A novel luminescent coordination polymer (CP) {Mn(H2abtc)(DMF)(H2O)2·2H2O}n (1), (H4abtc = 3,3′,5,5′-azobenzenete-tracarboxylic acid), has been successfully prepared by the solvothermal reaction of H4abtc and MnCl2·4H2O, which has been further characterized by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis (TGA), infrared (IR) spectrum and powder X-ray diffraction (PXRD). 1 can serve as a potential dual response luminescence sensor for picric acid (PA) and CrO42− via luminescence quenching with good selectivity and sensitivity. The quenching behavior of PA toward 1 can be ascribed to the combined effects of electron and resonance energy transfer mechanisms. And the quenching phenomenon of CrO42− to 1 can be explained by the electron transfer mechanism.

Graphical abstract

A novel luminescent Mn(II)-based coordination polymer 1 has been successfully prepared. 1 can serve as a potential dual response luminescence sensor for Picric acid (PA) and CrO42− with good selectivity and sensitivity.

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Acknowledgements

Natural Science Foundation of Shanxi Province China (201901D111139).

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Authors and Affiliations

  1. School of Science, North University of China, Taiyuan, 030051, Shanxi, China

    Zi-Yang Wang & Ya-Ru Liu

  2. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150080, China

    Yuan-Lin Duan, Rui Zhou & Xiao Zhang

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  1. Zi-Yang Wang
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  2. Ya-Ru Liu
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  3. Yuan-Lin Duan
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  4. Rui Zhou
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  5. Xiao Zhang
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Correspondence to Ya-Ru Liu or Xiao Zhang.

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Wang, ZY., Liu, YR., Duan, YL. et al. Manganese(II)-based coordination polymer as a bi-responsive luminescent sensor for highly selective detection of picric acid and CrO42− ion. Transit Met Chem 47, 85–92 (2022). https://doi.org/10.1007/s11243-022-00492-w

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  • DOI: https://doi.org/10.1007/s11243-022-00492-w

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