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Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior

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Abstract

Two poly-iodine aromatic tricarboxylate complexes: {(Me2NH2)[Mn(TIBTC)(2, 2'-bipy)(H2O)]}n (1) and {(Me2NH2)[Co(TIBTC)(DMA)]}n (2) (DMA = N, N-dimethylacetamide), were designed and synthesized by the hydrothermal synthetic methods (TIBTC = 2, 4, 6-triiodo-1, 3, 5-benzenetricarboxylic acid). Complexes were characterized by microanalysis. The crystal structures of complexes 1 and 2 were determined by X-ray single-crystal diffraction. Complex 1 is a 3D network supramolecular network structure connected by the hydrogen bonds, and complex 2 is a 3D network structure. To explore their functional properties, we first investigated the adsorption capacity of complexes 1 and 2 for iodine capture in cyclohexane solution. The maximum adsorption capacity of complex 2 is 125 mg/g. Meanwhile, the adsorption kinetic curves fitting showed that complexes 1 and 2 all conformed to the pseudo-second-order curves.

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Acknowledgements

This work was supported by the Grants of the National Natural Science Foundation of China (No. 21571091) and Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, People’s Republic of China (Project No. 191001-K).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, People’s Republic of China

    He-Qun Cai, Chun-Hong Liu, Yu Xin, Chen Wang, Feng-Ying Bai & Yong-Heng Xing

  2. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Li-Xian Sun

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Cai, HQ., Liu, CH., Xin, Y. et al. Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior. Transit Met Chem 46, 633–644 (2021). https://doi.org/10.1007/s11243-021-00481-5

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