Synthesis, structure, and properties of two coordination polymers constructed from 5-(isonicotinamido)isophthalic acid

Abstract

Two three-dimensional (3D) coordination polymers, viz. [Ni(INAIP)(Him)(H2O)]·H2O (1) and [Fe(INAIP)(H2O)2]·H2O (2), were synthesized by reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP), NiSO4·6H2O/FeSO4·7H2O, and N-donor ligands, namely 1H-imidazole or 4,4′-bipyridine, under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicated that [Ni(INAIP)(Him)(H2O)]·H2O has a two-dimensional (2D) layer network structure with (6, 3) topology, while 2 shows a 3D fourfold interpenetrating framework with (103-b) topology. The thermal stability and magnetic and adsorption behavior in solid state of the complexes were investigated in detail. Moreover, the photocatalytic degradation of methylene blue (MB) over complex 1 was studied.

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Acknowledgements

This work was supported by the Fund of Hunan Provincial Natural Science Foundation of China (no. 2020JJ4148), the Scientific Research Fund of Hunan Provincial Education Department (no. 18A328), the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (no. GN19K03), and the Center for the Functionalization of Metal-Organic Frameworks Materials Studies (no. KYJG1802).

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Correspondence to Man-Sheng Chen.

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Chen, XL., Zhu, P., Deng, YF. et al. Synthesis, structure, and properties of two coordination polymers constructed from 5-(isonicotinamido)isophthalic acid. Transit Met Chem 46, 159–166 (2021). https://doi.org/10.1007/s11243-020-00432-6

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Keywords

  • Coordination polymers
  • Crystal structure
  • Adsorption
  • Carboxamide ligand