Reactions of [HOs3(CO)83-Ph2PCH(R)P(Ph)C6H4}] (R = H, Me) with Bu3SnH: synthesis and structure of bimetallic Os-Sn clusters

Abstract

Reactions of unsaturated [HOs3(CO)83-Ph2PCH(R)P(Ph)C6H4}] (R = H, Me) with Bu3SnH are examined. [HOs3(CO)83-Ph2PCH(R)P(Ph)C6H4}] reacts with Bu3SnH at room temperature to afford [H2Os3(CO)8(SnBu3){µ3-Ph2PCH(R)P(Ph)C6H4}] (1) via oxidative addition of the Sn‒H bond to the parent cluster. Heating 1 in refluxing toluene leads to the formation of [H2Os3(CO)7(SnBu3){µ3-Ph2PCH(R)P(Ph)C6H4}] (2) through decarbonylation. Cluster 2 exists in two isomeric forms in solution which has been probed by VT NMR spectroscopy. The new Os-Sn bimetallic clusters have been characterized by a combination of analytical and spectroscopic data together with single-crystal X-ray diffraction analysis.

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Acknowledgements

This research has been sponsored by the University Grants Commission of Bangladesh. We are grateful to Dr. Shaikh M. Mobin, Indian Institute of Technology Indore, for collection of X-ray data (1a and 1b). We also thank the Wazed Miah Science Research Center, Jahangirnagar University, Bangladesh, for providing some technical facilities required for this work.

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Correspondence to Shishir Ghosh or Shariff E. Kabir.

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Joy, M.T.R., Uddin, M.M., Bhoumik, N.C. et al. Reactions of [HOs3(CO)83-Ph2PCH(R)P(Ph)C6H4}] (R = H, Me) with Bu3SnH: synthesis and structure of bimetallic Os-Sn clusters. Transit Met Chem 46, 149–157 (2021). https://doi.org/10.1007/s11243-020-00431-7

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