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Synthesis, structures and physicochemical properties of two two-dimensional coordination polymers based on 3,5-di(1H-benzimidazol-1-yl)pyridine

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Abstract

Two-dimensional coordination polymers [Co(L)(PDA)·H2O]n (1) and [Cd(L)(OBA)·4H2O]n (2) [L = 3,5-di(1H-benzimidazol-1-yl)pyridine, H2PDA = 1,3-phenylenediacetic acid, H2OBA = 4,4′-oxybis(benzoic acid)] have been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The latter revealed that both complexes have 2D (4,4)-connected layer structures. These layers are linked by O–H···O and C–H···O hydrogen bonds to form a three-dimensional supramolecular framework, which is reinforced by π–π interactions. There is an antiferromagnetic interaction between the adjacent Co(II) centers in complex 1, while complex 2 displays interesting photoluminescence and is also a good photocatalyst for the degradation of methyl orange.

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Authors and Affiliations

  1. Department of Pharmaceutical Technology and Biological Engineering, Changzhou Institute of Engineering Technology, Changzhou, 213164, People’s Republic of China

    Hui-Ru Chen

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Chen, HR. Synthesis, structures and physicochemical properties of two two-dimensional coordination polymers based on 3,5-di(1H-benzimidazol-1-yl)pyridine. Transit Met Chem 44, 407–413 (2019). https://doi.org/10.1007/s11243-019-00316-4

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  • DOI: https://doi.org/10.1007/s11243-019-00316-4

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