Transition Metal Chemistry

, Volume 44, Issue 6, pp 507–514 | Cite as

Mizoroki–Heck cross-coupling reactions using palladium immobilized on DABCO-functionalized silica

  • Sanjay Jadhav
  • Seema Patil
  • Arjun Kumbhar
  • Santosh Kamble
  • Rajashri SalunkheEmail author


A heterogeneous palladium catalyst supported on silica modified by DABCO has been prepared by post-synthetic modification of silica gel. This heterogeneous catalytic system exhibits high activity and stability in the Mizoroki–Heck cross-coupling reaction of various aryl halides with olefins. The reaction proceeds efficiently under efficiently under mild mild reaction conditions and high yield, with the formation of E-isomers selectively. Moreover, we successfully established a gram-scale synthesis, and the catalyst was reused for up to ten catalytic cycles.



Author Sanjay Jadhav thanks the University Grants Commission, New Delhi, India, for the award of SAP-BSR fellowship.

Compliance with ethical standards

Conflicts of interest

The authors declare that they have no conflict of interest.


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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Sanjay Jadhav
    • 1
  • Seema Patil
    • 2
  • Arjun Kumbhar
    • 2
  • Santosh Kamble
    • 3
  • Rajashri Salunkhe
    • 1
    Email author
  1. 1.Department of ChemistryShivaji UniversityKolhapurIndia
  2. 2.Department of ChemistryP.D.V.P. CollegeTasgaonIndia
  3. 3.Department of ChemistryYashvantrao Chavan Institute of ScienceSataraIndia

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