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Polyoxometalate-based complexes with a flexible bis-imidazole-bis-amide ligand: structures, electrochemical and photocatalytic properties

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Abstract

Three different polyoxometalate (POM)-based complexes, [CoL(H2O)(α-Mo8O26)0.5]·4H2O (1), [NiL(H2O)(θ-Mo8O26)0.5]·4H2O (2) and [Ag2L2][HPMo12O40]·3H2O (3) (L = 1, 2 bis(1H-imidazole-4-carboxamido)ethyl) have been synthesized under hydrothermal conditions. The different heterometals lead to two types of polyoxomolybdates, specifically [α-Mo8O26]4− and [θ-Mo8O26]4− in complexes 1 and 2, respectively. In complex 1, the [α-Mo8O26]4− anions are linked into a 1D chain by [Co2L2(H2O)2]4+ cations. Replacing Co2+ with Ni2+, [θ-Mo8O26]4− anions were constructed in complex 2. In contrast, a discrete metal–organic cation [Ag2L2]2+ and Keggin-type [PMo12O40]3− anion resulted when Ag+ was used to prepare complex 3 in the presence of phosphoric acid. The electrochemical and photocatalytic properties of all three complexes were studied.

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References

  1. Hirano T, Uehara K, Kamata K, Mizuno N (2012) J Am Chem Soc 134:6425–6433

    Article  CAS  PubMed  Google Scholar 

  2. Wang XL, Li N, Tian AX, Ying J, Lin XL, Luan J, Yang Y (2014) Inorg Chem 53:7118–7129

    Article  CAS  PubMed  Google Scholar 

  3. Sartzi H, Miras HN, Nadal L, Long DL, Cronin L (2015) Angew Chem Int Ed 127:15708–15492

    Article  Google Scholar 

  4. Wang XL, Zhang R, Wang X, Lin HY, Liu GC (2016) Inorg Chem 55:6384–6393

    Article  CAS  PubMed  Google Scholar 

  5. Liu YP, Zhao SF, Guo SX, Bond AM, Zhang J (2016) J Am Chem Soc 138:2617–2628

    Article  CAS  PubMed  Google Scholar 

  6. Korenev VS, Boulay AG, Dolbecq A, Sokolov MN, Hijazi A, Floquet S, Fedin VP, Cadot E (2010) Inorg Chem 49:9740–9742

    Article  CAS  PubMed  Google Scholar 

  7. Hao XL, Ma YY, Wang YH, Zang HY, Li YG (2014) Cryst Eng Commun 16:10017–10027

    Article  CAS  Google Scholar 

  8. Du HJ, Wang CH, Li Y, Niu YY, Hou HW (2015) RSC Adv 5:74065–74074

    Article  CAS  Google Scholar 

  9. Lan YQ, Li SL, Wang XL, Shao KZ, Du DY, Zang HY, Su ZM (2008) Inorg Chem 47:8179–8187

    Article  CAS  PubMed  Google Scholar 

  10. Lan YQ, Li S, Wang XL, Shao KZ, Su ZM, Wang EB (2008) Inorg Chem 47:529–534

    Article  CAS  PubMed  Google Scholar 

  11. Du XD, Li CH, Zhang Y, Liu S, Ma Y, You XZ (2011) Cryst Eng Commun 13:2350–2357

    Article  CAS  Google Scholar 

  12. Kan WQ, Yang J, Liu YY, Ma JF (2012) Inorg Chem 51:11266–11278

    Article  CAS  PubMed  Google Scholar 

  13. Xu N, Zhang JW, Wang XL, Liu GC, Li TJ (2016) Dalton Trans 45:760–767

    Article  CAS  PubMed  Google Scholar 

  14. Zhao J, Wang YN, Dong WW, Wu YP, Li DS, Zhang QC (2016) Inorg Chem 55:3265–3271

    Article  CAS  PubMed  Google Scholar 

  15. Sha JQ, Li MT, Sun JW, Zhang YN, Yan PF, Li GM (2013) Dalton Trans 42:7803–7809

    Article  CAS  PubMed  Google Scholar 

  16. Wang LD, Liu TT (2018) Chin J Catal 39:327–333

    Article  CAS  Google Scholar 

  17. Cui JW, Hou SX, Heckeb KV, Cui GH (2017) Dalton Trans 46:2892–2903

    Article  CAS  PubMed  Google Scholar 

  18. Wang XL, Zhang S, Wang X, Liu GC, Lin HY, Zhang HX (2017) Dalton Trans 46:16580–16588

    Article  CAS  PubMed  Google Scholar 

  19. Sarkar M, Biradha K (2006) Cryst Growth Des 6:202–208

    Article  CAS  Google Scholar 

  20. Sheldrick GM (2008) Acta Crystallogr Sect A Found Crystallogr 64:112–122

    Article  CAS  Google Scholar 

  21. Brown ID, Altermatt D (1985) Acta Crystallogr Sect B Struct Sci 41:244–247

    Article  Google Scholar 

  22. Tian AX, Ning YL, Wang XL (2015) Cryst Eng Commun 44:10499–10507

    CAS  Google Scholar 

  23. Saeed A, Ashraf Z, Erben MF, Simpson J (2017) J Mol Struct 1129:283–291

    Article  CAS  Google Scholar 

  24. Wang XL, Xu C, Lin HY, Liu GC, Luan J, Chang ZH (2013) RSC Adv 3:3592–3598

    Article  CAS  Google Scholar 

  25. Fernandes DM, Teixeira A, Freire C (2015) Langmuir 31:1855–1865

    Article  CAS  PubMed  Google Scholar 

  26. Dolbecq A, Mialane P, Keita B, Nadjo L (2012) J Mater Chem 22:24509–24521

    Article  CAS  Google Scholar 

  27. Wang P, Wang XP, Yuan Y, Zhu GY (2000) J NonCryst Solids 277:22–29

    Article  CAS  Google Scholar 

  28. Liu B, Yu ZT, Yang J, Hua W, Liu YY, Ma JF (2011) Inorg Chem 50:8967–8972

    Article  CAS  PubMed  Google Scholar 

  29. Tang J, Zou Z, Yin J, Ye J (2003) Chem Phys Lett Elsevier 382:175–179

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21671025, 21471021, 201401010 and YJC20170021) and Program for Distinguished Professor of Liaoning Province (No. 2015399).

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Authors and Affiliations

  1. Department of Chemistry, Bohai University, Jinzhou, 121000, People’s Republic of China

    Xiuli Wang, Xiang Pan, Xiang Wang, Guocheng Liu, Hongyan Lin & Shan Zhang

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  1. Xiuli Wang
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  2. Xiang Pan
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  3. Xiang Wang
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  4. Guocheng Liu
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  5. Hongyan Lin
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  6. Shan Zhang
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Correspondence to Xiuli Wang.

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Wang, X., Pan, X., Wang, X. et al. Polyoxometalate-based complexes with a flexible bis-imidazole-bis-amide ligand: structures, electrochemical and photocatalytic properties. Transit Met Chem 44, 207–217 (2019). https://doi.org/10.1007/s11243-018-0284-7

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