3-Aminoquinazoline–phosphine ligands and their ruthenium(II) complexes: application in catalytic hydrogenation and transfer hydrogenation reactions

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Abstract

3-Aminoquinazolinone–phosphine proligands (5ae) and their Ru(II) complexes (6ae) were prepared and characterized by NMR (1H, 13C, 31P{1H}), FTIR and microanalysis. The 3-aminoquinazolinone–phosphine ligands were found to coordinate with the Ru(II) center via their phosphorus and nitrogen atoms. The Ru(II) complexes were applied as catalysts for the hydrogenation and transfer hydrogenation of prochiral ketones. The results showed that these complexes are efficient transfer hydrogenation catalysts.

Notes

Acknowledgements

This work was supported by the Osmaniye Korkut Ata University and the Scientific and Technological Research Council of Turkey (Project Number: 109T801). The authors also thank to Prof. Dr. Sabri Ulukanlı for the synthesis of 3-aminoquinazolinones.

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of Arts and SciencesOsmaniye Korkut Ata UniversityOsmaniyeTurkey
  2. 2.Department of Chemistry, Faculty of Arts and SciencesMersin UniversityMersinTurkey

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