Skip to main content
Log in

Cobalt(II), nickel(II) and copper(II) complexes of a Schiff base ligand: synthesis, structural characterization and luminescence properties

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

A Schiff base ligand (HL), 2,4-dimethoxy-N-(5-chloro-2-hydroxybenzylidene)-benzenamine, derived from 5-chloro-2-hydroxybenzaldehyde and 2,4-dimethoxyaniline, and its metal complexes [Co(L)2]·CH3OH (1), [Ni(L)2] (2), [Cu(L)2] (3) have been synthesized. The compounds were characterized by analytical and spectroscopic methods. In addition, the structures of the Schiff base HL and its Co(II) complex were determined by single-crystal X-ray analysis. The Co(II) center is six-coordinate, being coordinated to two imine nitrogen, two phenolate oxygen and two methoxy oxygen atoms of two crystallographically independent Schiff base ligands. Luminescence properties of HL and its complexes were investigated both in solution and in the solid state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Scheme 2
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 3
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Poulter N, Donaldson M, Mulley G, Duque L, Waterfield N, Shard AG, Spencer S, Tobias A, Jenkins A, Johnson AL (2011) New J Chem 35:1477–1484

    Article  CAS  Google Scholar 

  2. Khorshidifard M, Rudbari HA, Kazemi-Delikani Z, Mirkhani V, Azadbakht R (2015) J Mol Struct 1081:494–505

    Article  CAS  Google Scholar 

  3. Hariprasath K, Deepthi B, Babu IS, Venkatesh P, Sharfudeen S, Soumya V (2012) J Chem Pharm Res 2:496–499

    Google Scholar 

  4. Ghosh P, Roy BG, Mukhopadhyay SK, Banerjee P (2015) RSC Adv 5:27387–27392

    Article  CAS  Google Scholar 

  5. Shabbir M, Akhter Z, Ahmad I, Ahmed S, Ismail H, Mirza B, McKee V, Bolte M (2016) J Mol Struct 1116:84–92

    Article  CAS  Google Scholar 

  6. Pal MK, Kushwah N, Wadawale AP, Dey S, Sudarsan V, Jain VK (2016) J Organomet Chem 808:128–133

    Article  CAS  Google Scholar 

  7. Tümer M, Güngör SA, Çiftaslan AR (2016) J Lumin 170:108–120

    Article  Google Scholar 

  8. Bruker (1998). APEX2 and SAINT Bruker AXS Inc

  9. Köse M, Ceyhan G, Tümer M, Demirtaş İ, Gönül İ, McKee V (2015) Spectrochim Acta A 137:477–485

    Article  Google Scholar 

  10. Sheldrick GM (2008) Acta Cryst A64:112

    Article  Google Scholar 

  11. Galini M, Salehi M, Kubicki M, Amiri A, Khaleghian A (2017) Inorg Chim Acta 461:167–173

    Article  CAS  Google Scholar 

  12. Kokare DG, Kamat V, Naik K, Nevrekar A, Kotian A, Revankar VK (2017) J Mol Struct 1127:289–295

    Article  CAS  Google Scholar 

  13. Rad M, Dehghanpour S, Fatehfard S, Gholamrezazadeh C, Mahmoudi A (2016) Polyhedron 106:10–17

    Article  CAS  Google Scholar 

  14. El-Sonbati AZ, Diaba MA, El-Bindarya AA, Mohamed GG, Morgan M, Abou-Dobara MI, Nozha SG (2016) J Mol Liq 215:423–442

    Article  CAS  Google Scholar 

  15. Jing C, Wang C, Yan K, Zhao K, Sheng G, Qua D, Niu F, Zhu H, You Z (2016) Bioorg Med Chem 24:270–276

    Article  CAS  Google Scholar 

  16. Arun T, Subramanian R, Raman N (2016) J Photochem Photobiol B 154:67–76

    Article  CAS  Google Scholar 

  17. Kavitha P, Reddy KL (2016) Arab J Chem 9:596–605

    Article  CAS  Google Scholar 

  18. Matijević-Sosa J, Vinković M, Vikić-Topić D (2006) Croat Chem Acta 79:489–495

    Google Scholar 

  19. Abd-Elzaher MM, Labib AA, Mousa HA, Moustafa SA, Ali MM, El-Rashedy AA (2016) Beni-Seuf Univ J Appl Sci 5:85–96

    Google Scholar 

  20. Salehi M, Ghasemi F, Kubicki M, Asadi A, Behzad M, Ghasemi MH, Gholizadeh A (2016) Inorg Chim Acta 453:238–246

    Article  CAS  Google Scholar 

  21. Grivani G, Vakili M, Khalaji AD, Bruno G, Rudbari HA, Taghavi M (2016) J Mol Struct 1116:333–339

    Article  CAS  Google Scholar 

  22. Rudbari HA, Iravani MR, Moazam V, Askari B, Khorshidifard M, Habibi N, Bruno G (2016) J Mol Struct 1125:113–120

    Article  Google Scholar 

  23. Sallam SA, Abbas AM (2013) J Lumin 136:212–220

    Article  CAS  Google Scholar 

  24. Back DF, Oliveira GM, Fontana LA, Ramao BF, Roman D, Iglesias BA (2015) J Lumin 1100:264–271

    CAS  Google Scholar 

  25. Bhattacharyya A, Harms K, Chattopadhyay S (2014) Inorg Chem Commun 48:12–17

    Article  CAS  Google Scholar 

  26. Manjunath M, Kulkarni AD, Bagihalli GB, Malladi S, Patil SA (2017) J Mol Struct 1127:314–321

    Article  CAS  Google Scholar 

  27. Fekri A, Zaky R (2016) J Org Chem 818:15–27

    Article  CAS  Google Scholar 

  28. Abdel-Kader NS, El-Ansary AL, El-Tayeb TA, Elnagdi MMF (2016) J Photochem Photobiol A 321:223–237

    Article  CAS  Google Scholar 

  29. Abdel-Rahman LH, Abu-Dief AM, Newair EF, Hamdan SK (2016) J Photochem Photobiol B 160:18–31

    Article  CAS  Google Scholar 

  30. Das K, Datta A, Roy S, Clegg JK, Garribba E, Sinha C, Kara H (2014) Polyhedron 78:62–71

    Article  CAS  Google Scholar 

  31. Roy S, Choubey S, Bhar K, Khan S, Mitra P, Ghosh BK (2013) J Mol Struct 1051:328–335

    Article  CAS  Google Scholar 

  32. Kumari R, Varghese A, George L (2016) J Lumin 179:518–526

    Article  CAS  Google Scholar 

  33. Roy S, Sarkar BN, Bhar K, Satapathi S, Mitra P, Ghosh BK (2013) J Mol Struct 1037:160–169

    Article  CAS  Google Scholar 

  34. Chavan SS, Pawal SB, Lolage SR (2017) J Lumin 181:261–268

    Article  CAS  Google Scholar 

  35. Pal MK, Kushwah N, Wadawale AP, Manna D, Sudarsan V, Ghanty TK, Jain VK (2015) J Org Chem 776:98–106

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to İlyas Gönül.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 580 kb)

Appendix: Supplementary material

Appendix: Supplementary material

CCDC 1509986 and 1509987 contain the supplementary crystallographic data for the Schiff base HL and its complex [Co(L)2]·MeOH, respectively. The data can be obtained free of charge via www.ccdc.cam.ac.uk/datarequest/cif, by e-mailing data request@ccdc.cam.ac.uk or by contacting The Cambridge Crystallographic Data Centre 12 Union Road Cambridge CB2 1EZ, UK Fax: +44(0)1223-336033.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gönül, İ., Fakı, E., Ay, B. et al. Cobalt(II), nickel(II) and copper(II) complexes of a Schiff base ligand: synthesis, structural characterization and luminescence properties. Transit Met Chem 43, 73–81 (2018). https://doi.org/10.1007/s11243-017-0195-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-017-0195-z

Navigation