Transition Metal Chemistry

, Volume 43, Issue 2, pp 103–113 | Cite as

Syntheses, structures and properties of a series of nickel(II) complexes derived from amino-5-mercapto-1,3,4-thiadiazole

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Abstract

Four complexes possessing photocatalytic activity, namely [Ni(AMT)2(EDA)2]2 (1), [Ni4(AMT)63-OH)2(H2O)6] (2), [Ni4(AMT)63-OH)2(H2O)6]·4H2O (3) and [Ni4(AMT)63-OH)2(H2O)6]·2H2O (4) (AMT = amino-5-mercapto-1,3,4-thiadiazole and EDA = diethanolamine) have been obtained from solvothermal reactions and characterized by physico-chemical and spectroscopic methods. Although complexes 14 were prepared from common reactants (nickel nitrate and AMT), the use of different organic amines and reaction conditions lead to the observed differences in their structures. Complex 1 is mononuclear, while complex 2 is a {Ni4} cluster. Complexes 34 are expanded into supramolecular structures by hydrogen bonding interactions, but differences in their lattice water molecules lead to the different supramolecular structures. Photocatalytic studies reveal that complex 4 exhibits good catalytic activity for the degradation of the organic dye methylene blue.

Graphical Abstract

Four complexes possessing photocatalytic activity and constructed from the late transition metal Ni(II) and the 2-amino-5-mercapto-1,3,4-thiadiazole ligand have been obtained in solvothermal conditions. Although complexes 14 were prepared from common reactants (nickel nitrate and AMT), the use of different organic amines and reaction conditions lead to the observed differences in their structures. Complex 1 is mononuclear, while complex 2 is a {Ni4} cluster. Complexes 34 are expanded into supramolecular structures by hydrogen bonding interactions, but differences in their lattice water molecules lead to the different supramolecular structures. Photocatalytic studies reveal that complex 4 exhibits good catalytic activity for the degradation of the organic dye methylene blue.

Notes

Acknowledgements

This work was supported by the Program for National Nature Science Foundation of China (Nos. 21271024 and 20971014) and Foundation the 111 Project (B07012) in China.

Supplementary material

11243_2017_188_MOESM1_ESM.doc (384 kb)
Supplementary material 1 (DOC 384 kb)

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Copyright information

© Springer International Publishing AG 2018

Authors and Affiliations

  1. 1.Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijingChina

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