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Syntheses, crystal structures and magnetic properties of four tetrahydrofuran-2,3,4,5-tetracarboxylato bridged transition metal complexes with N-donor heteroaromatic co-ligands

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Abstract

Four tetrahydrofuran-2,3,4,5-tetracarboxylato complexes, Cu(bpy)(H2THFTC) (1), [Cu(phen)(H2THFTC)]·0.5H2O (2), [Mn(phen)(H2THFTC)]·0.5H2O (3) and [Co4(H2O)4(phen)4(THFTC)2]·4H2O (4) (H4THFTC = tetrahydrofuran-2,3,4,5-tetracarboxylic acid, phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine) were synthesized in aqueous solution or under hydrothermal conditions, and characterized. In compounds 1–3, the metal centers are bridged by tetrahydrofuran-2,3,4,5-tetracarboxylate anions to form 1D chains, which are further assembled into 2D supramolecular layers based on interchain π···π interactions. Compound 4 consists of tetranuclear [Co4(H2O)4(phen)4(THFTC)2] complex molecules and lattice water molecules. The complex molecules are interconnected into hydrogen-bonded chains along the [100] direction, and interdigitation of phen ligands with interchain π···π stacking interactions assembles the hydrogen-bonded chains into 2D supramolecular layers parallel to the (010) plane. Variable-temperature magnetic measurements show an overall weak ferromagnetic behavior for complexes 1 and 2 and antiferromagnetic behavior for complexes 3 and 4.

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Acknowledgements

This project was supported by the Public Projects of Zhejiang Province (2017C33008) and Ningbo Natural Science Foundation (2017A610068). Honest thanks are also extended to the K. C. Wong Magna Fund in Ningbo University.

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Authors and Affiliations

  1. Joint Laboratory for Environmetal Test and Photocatalytic Research of Ningbo University–Zhejiang Zhonghao Applied Engineering Technology Institute Co., Ltd., Research Center of Applied Solid State Chemistry, Chemistry Institute for Synthesis and Green Application, Ningbo University, Ningbo, 315211, Zhejiang, People’s Republic of China

    Lin-Xia Zhou, Wei Xu, Xiao-Yan Han, Zhen-Xiu Si & Yue-Qing Zheng

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  1. Lin-Xia Zhou
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  2. Wei Xu
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  3. Xiao-Yan Han
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Corresponding author

Correspondence to Yue-Qing Zheng.

Electronic supplementary material

Below is the link to the electronic supplementary material.

11243_2017_184_MOESM1_ESM.docx

Crystallographic data for compounds 1–4 deposited with the Cambridge Crystallographic Data Center, CCDC-1515633 (1), -1515634 (2), -1515635 (3) and -1515636 (4). [CCDC, 12 Union Road, Cambridge CB2 1EZ, United Kingdom. Fax: (44)1223-336-033. E-mail: deposit@ccdc.cam.ac.uk. Website: http://www.ccdc.cam.ac.uk]. Selected interatomic distances and bond angles tables are described in Tables S2.1 to S2.3 for compounds 1–4, PXRD patterns, infrared spectra and TG curves of complexes 1–4 are showed in Figs. S1–S3 (DOCX 640 kb)

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Zhou, LX., Xu, W., Han, XY. et al. Syntheses, crystal structures and magnetic properties of four tetrahydrofuran-2,3,4,5-tetracarboxylato bridged transition metal complexes with N-donor heteroaromatic co-ligands. Transit Met Chem 42, 763–772 (2017). https://doi.org/10.1007/s11243-017-0184-2

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  • DOI: https://doi.org/10.1007/s11243-017-0184-2

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