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Structural and magnetic properties of manganese and nickel clusters with 9,10-phenanthrenedione-9-oxime ligands

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Abstract

Two complexes of 9,10-phenanthrenedione-9-oxime (HL), [MnIIIMnIIMnIIIL6](OH)2·3DMF (1) and [Ni2L4(H2O)2]·3DMF (2), were obtained from the reactions of 9,10-phenanthrenedione dioxime with Mn2+ and 9,10-phenanthrenedione-9-oxime with Ni2+, respectively. Thus, 9,10-phenanthrenedione dioxime was transformed into HL during the course of the reaction. Complex 1 presents a mixed-valence linear trinuclear skeleton with the central Mn(II) atom linked to the two peripheral Mn(III) atoms by triple oximato bridges. Complex 2 features a dinuclear structure with the two Ni(II) atoms bridged by two oximato bridges. The magnetic properties of the two complexes were investigated.

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Acknowledgements

We gratefully thank the financial support by Scientific Research Fund of Hunan Provincial Education Department (15C1234), Innovation Project of Guangxi Graduate Education (YCSZ2016036), and National Natural Foundation of China (Grant No. 21261004).

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Authors and Affiliations

  1. Department of Biological and Chemical Engineering, Shaoyang University, Shaoyang, 422000, Hunan, People’s Republic of China

    Xiaofang Li

  2. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Bo Li

  3. School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Zhaobo Hu, Haiyan Cheng, Qin Zhao & Zilu Chen

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  1. Xiaofang Li
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  2. Bo Li
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  3. Zhaobo Hu
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  6. Zilu Chen
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Correspondence to Xiaofang Li, Bo Li or Zilu Chen.

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Li, X., Li, B., Hu, Z. et al. Structural and magnetic properties of manganese and nickel clusters with 9,10-phenanthrenedione-9-oxime ligands. Transit Met Chem 42, 421–426 (2017). https://doi.org/10.1007/s11243-017-0145-9

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  • DOI: https://doi.org/10.1007/s11243-017-0145-9

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