Abstract
Four organic–inorganic hybrid selenidostannates, namely [H2en][H2dien][Fe(dien)2]2(Sn2Se6)2 (1), [Fe(dien)2]2Sn2Se6 (2), [Fe(dien)2]FeSnSe4 (3), and [Mn(dien)2]MnSnSe4 (4) (en = ethylenediamine; dien = diethylenetriamine), were prepared in different solvents under solvothermal conditions. Complexes 1 and 2 consist of discrete [Sn2Se6]4− and [Fe(dien)2]2+ ions, as well as organic cations [H2en]2+ and [H2dien]2+ in 1. The dimeric [Sn2Se6]4− anion is formed by two SnSe4 tetrahedra via edge-sharing. Complexes 3 and 4 are composed of one-dimensional polyanions [TMSnSe 2−4 ] n plus [TM(dien)2]2+ counter cations (TM = Fe, Mn). In the [TMSnSe 2−4 ] n anionic chain, the TM and Sn atoms are located at the same metal site with a ratio of 0.5/0.5. The TM1/2Sn1/2Se4 tetrahedra are interlinked via edge-sharing, forming the heterometallic [TMSnSe 2−4 ] n polymeric anion. The [TM(dien)2]2+ cations in 1–2 and 3–4 have u-fac and mer configurations, respectively. In all four crystal structures, the anions and cations are connected into extended structures via weak N–H···Se hydrogen bonds. The band gaps of complexes 1–4 calculated from the solid-state UV–vis diffuse reflectance spectra were at 2.58, 2.60, 2.21, and 2.25 eV, respectively. Thermogravimetric analyses show that complex 1 decomposes in three steps, while complexes 2–4 each decompose in one step.
Similar content being viewed by others
References
Li J, Chen Z, Wang RJ, Proserpio DM (1999) Coord Chem Rev 190–192:707–975
Zimmermann C, Anson CE, Weigend F, Clérac R, Dehnen S (2005) Inorg Chem 44:5686–5695
Liao JH, Marking GM, Hsu KF, Matsushita Y, Ewbank MD, Borwick R, Cunningham P, Rosker MJ, Kanatzidis MG (2003) J Am Chem Soc 125:9484–9493
Zheng NF, Bu XH, Wang B, Feng PY (2002) Science 298:2366–2369
Dehnen S, Zimmermann C (2002) Z Anorg Allg Chem 628:2463–2469
Pienack N, Näther C, Bensch W (2009) Eur J Inorg Chem 7:937–946
Han XH, Meng JL, Xu J, Liu XJ, Liu D, Wang C (2016) Inorg Chem Commun 63:42–47
Xiong WW, Miao JW, Ye KQ, Wang Y, Liu B, Zhang QC (2015) Angew Chem Int Ed 54:546–550
Du CF, Li JR, Feng ML, Zou GD, Shen NN, Huang XY (2015) Dalton Trans 44:7364–7372
Lin YM, Dehnen S (2011) Inorg Chem 50:7913–7915
Tang CY, Wang F, Lu JL, Jia DX, Jiang WQ, Zhang Y (2014) Inorg Chem 53:9267–9273
Luo HB, Ren LT, Ning WH, Liu SX, Liu JL, Ren XM (2016) Adv Mater 28:1663–1667
Zhang B, Li J, Du CF, Feng ML, Huang XY (2016) Inorg Chem 55:10855–10858
Xiong WW, Li PZ, Zhou TH, Tok AIY, Xu R, Zhao YL, Zhang QC (2013) Inorg Chem 52:4148–4150
Xiong WW, Miao JW, Li PZ, Zhao YL, Liu B, Zhang QC (2014) J Solid State Chem 218:146–150
Manos MJ, Jang JI, Ketterson JB, Kanatzidis MG (2008) Chem Commun 8:972–974
Wang YL, Feng ML, Wang KY, Li JR, Wang ZP, Zou GD, Huang XY (2013) Inorg Chem Commun 33:10–14
Lu JL, Shen YL, Wang F, Tang CY, Zhang Y, Jia DX (2015) Z Anorg Allg Chem 641:561–567
Wendlandt WW, Hecht HG (1966) Reflectance Spectroscopy. Interscience Publishers, New York
Sheldrick GM (1997) SHELXS-97, program for structure solution. Universität of Göttingen, Germany
Sheldrick GM (1997) SHELXL-97, Program for structure refinement. Universität of Göttingen, Germany
Liang JJ, Chen JF, Zhao J, Pan YL, Zhang Y, Jia DX (2011) Z Anorg Allg Chem 637:445–449
Stähler R, Näther C, Bensch W (2001) Eur J Inorg Chem 7:1835–1840
Kiebach R, Bensch W, Hoffmann RD, Pöttgen R (2003) Z Anorg Allg Chem 629:532–538
Keene FR, Searle GH (1972) Inorg Chem 11:148–156
Yoshikawa Y, Yamasaki K (1972) Bull Chem Soc Jpn 45:179–183
Xiong WW, Li PZ, Zhou TH, Zhao YL, Xu R, Zhang QC (2013) J Solid State Chem 204:86–90
Lekse JW, Leverett BM, Lake CH, Aitken JA (2008) J Solid State Chem 181:3217–3222
Lekse JW, Moreau MA, McNerny KL, Yeon J, Halasyamani PS, Aitken JA (2009) Inorg Chem 48:7516–7518
Brandmayer MK, Clerac R, Weigend F, Dehnen S (2004) Chem Eur J 10:5147–5157
Thiele G, Peter S, Schwarzer M, Ruzin E, Clerac R, Staesche H, Rosser C, Roling B, Dehnen S (2012) Inorg Chem 51:3349–3351
Pienack N, Möller K, Näther C, Bensch W (2007) Solid State Sci 9:1110–1114
Chen JF, Jin QY, Pan YL, Zhang Y, Jia DX (2009) Chem Commun 46:7212–7214
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant No. 21171123) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Sun, P., Liu, S., Han, J. et al. Solvothermal syntheses, crystal structures, and optical and thermal properties of transition metal selenidostannates. Transit Met Chem 42, 387–393 (2017). https://doi.org/10.1007/s11243-017-0141-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11243-017-0141-0