Transition Metal Chemistry

, Volume 42, Issue 1, pp 85–93 | Cite as

Synthesis, crystal structures, characterization and antimicrobial activities of 5-hydroxyisophthalate complexes

  • Alper Tolga Çolak
  • Handan GünayEmail author
  • Ersin Temel
  • Orhan Büyükgüngör
  • Ferdağ Çolak


Two 5-hydroxyisophthalate complexes of nickel(II), formulated as [Ni(μ-Hhip)(2-hepy)2] n (1) and [Ni2(μ-Hhip)2(dap)4] n (2) (H3hip = 5-hydroxyisophthalic acid, 2-hepy = 2-(2-hydroxyethyl)pyridine, dap = 1,3-diaminopropane), have been synthesized and characterized by chemical and spectroscopic methods. The molecular structures of the complexes have been determined by single-crystal X-ray diffraction analysis. The Ni(II) centres have distorted octahedral geometries in both crystals. Furthermore, both complexes have 1D chain structures in which the individual chains are linked together via hydrogen bonds to give 3D frameworks. Evaluation of the complexes by the agar diffusion method showed that they have weak antibiotic activities against the tested microorganisms.


Antimicrobial Activity Coordination Polymer Supramolecular Network Distorted Octahedral Geometry Monoclinic Crystal System 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Supplementary material

11243_2016_109_MOESM1_ESM.docx (703 kb)
Supplementary material 1 (DOCX 702 kb)


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Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • Alper Tolga Çolak
    • 1
  • Handan Günay
    • 2
    Email author
  • Ersin Temel
    • 3
  • Orhan Büyükgüngör
    • 4
  • Ferdağ Çolak
    • 5
  1. 1.Department of Chemistry, Faculty of Arts and SciencesDumlupınar UniversityKutahyaTurkey
  2. 2.Department of Chemistry Technology, Vocational High SchoolAvrasya UniversityPelitliTurkey
  3. 3.Department of Electric and Energy, Technical Sciences Vocational High SchoolGiresun UniversityGiresunTurkey
  4. 4.Department of Physics, Faculty of Arts and SciencesOndokuz Mayıs UniversityKurupelitTurkey
  5. 5.Department of Biology, Faculty of Arts and SciencesDumlupınar UniversityKutahyaTurkey

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