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Syntheses, crystal structures, and DNA binding and catalytic properties of two transition metal coordination polymers constructed from 5-aminoisophthalic acid and bis-benzimidazole ligands

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Abstract

Two mixed-ligand transition metal coordination polymers, {[Co(aip)(bbp)]·(H2O)} n (1) and {[Ni2(aip)(Hbbop)2]·(H2O)2} n (2) (H2aip = 5-aminoisophthalic acid, bbp = 1,3-bis(benzoimidazol-2-yl)propane, H2bbop = 1,3-bis(benzimidazol-2-yl)-2-oxapropane), were synthesized and characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction, and thermogravimetric analyses. Complex 1 has a 1D chain structure, while 2 has a 3-connected 2D network with (63) topology. Both structures are further connected by hydrogen bonds and π–π stacking interactions to form the 3D supramolecular architectures. DNA binding and catalytic properties of the two complexes were investigated.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20971076).

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Authors and Affiliations

  1. State Key Laboratory Base of Eco-chemical Engineering, Laboratory of Inorganic Synthesis and Applied Chemistry, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

    Yong-Hong Wen, Xiao-Wei Mu & Hui-Ling Wen

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  1. Yong-Hong Wen
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  2. Xiao-Wei Mu
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  3. Hui-Ling Wen
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Correspondence to Yong-Hong Wen.

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Wen, YH., Mu, XW. & Wen, HL. Syntheses, crystal structures, and DNA binding and catalytic properties of two transition metal coordination polymers constructed from 5-aminoisophthalic acid and bis-benzimidazole ligands. Transit Met Chem 41, 675–683 (2016). https://doi.org/10.1007/s11243-016-0068-x

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