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Electrochemical and in situ spectroelectrochemical properties of metal-free and metallophthalocyanines containing α-naphtholbenzein groups on the peripheral positions

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Abstract

Phthalocyanine (Pc) compounds-containing α-naphtholbenzein units have been synthesized and characterized by spectroscopic data and elemental analysis. The redox properties of the compounds were investigated by cyclic and square wave voltammetry, controlled-potential coulometry and in situ spectroelectrochemistry in DMSO and compared with the free phthalonitrile ligand. The Pc compounds displayed common metal and/or ring-based reduction and oxidation processes. However, electrochemical measurements clearly suggested that the substituents involving anthraquinone units are redox active and so have a considerable effect on the redox processes of these compounds.

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Acknowledgments

This work was supported by the Scientific and Technological Research Council of Turkey (TUBİTAK) (Project No: 113Z860) and partly by The Turkish Academy of Sciences (TUBA).

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Authors and Affiliations

  1. Department of Chemistry, Karadeniz Technical University, 61080, Trabzon, Turkey

    Meltem Betül Sağlam

  2. Department of Chemistry, Marmara University, 34722, Göztepe, Istanbul, Turkey

    Ali Rıza Özkaya

Authors
  1. Meltem Betül Sağlam
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  2. Ali Rıza Özkaya
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Correspondence to Meltem Betül Sağlam or Ali Rıza Özkaya.

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Sağlam, M.B., Özkaya, A.R. Electrochemical and in situ spectroelectrochemical properties of metal-free and metallophthalocyanines containing α-naphtholbenzein groups on the peripheral positions. Transit Met Chem 41, 605–612 (2016). https://doi.org/10.1007/s11243-016-0059-y

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