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Hydrostable coordination polymers of a methyl-functionalized 4,4′-bipyridine ligand: structure, stability, magnetic and luminescent properties

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Abstract

The reactions of aromatic dicarboxylic acids and methyl-functionalized 4,4′-bipyridine ligands with metal salts under hydrothermal conditions generated four structurally diverse cobalt(II), zinc(II) and cadmium(II) coordination polymers, [Co(CH3-BDC)(dmbpy)0.5] n (1), [Cd(OH-HBDC)2(dmbpy)] n (2), [Zn(NDC)(dmbpy)] n , (3) and {[Cd(DBA)(dmbpy)0.5]·2H2O} n (4) (CH3–H2BDC = 5-methylisophthalic acid, OH–H2BDC = 5-hydroxyisophthalic acid, H2NDC = 1,4-naphthalenedicarboxylic acid, H2DBA = 4,4′-methylenedibenzoic acid, dmbpy = 2,2′-dimethyl-4,4′-bipyridine). All four complexes have been structurally characterized by X-ray crystallography. Complex 1 shows a 3D jsm topology structure with two 1D channels parallel to the a and b axes. Complex 2 has a zigzag chain in which the OH-HBDC ligands point alternately up and down. Complexes 3 and 4 show 2D (4,4) networks when the dinuclear metal centers and their ligands are regarded as nodes and linkers, respectively. Complex 3 also shows twofold interpenetration with 1D channels along the b axis. Two nets of complex 4 interlock in parallel, giving rise to a polycatenated layer (2D → 2D). Thermogravimetric and chemical stabilities, magnetic and luminescent properties of these complexes were investigated.

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Acknowledgments

This work was supported by the Distinguished Young Talents in Higher Education of Guangdong Province (2014KQNCX222), the Natural Science Foundation of Guangdong Province (2015A030310407), the Natural Science Foundation of Zhaoqing University (201532), the characteristics of innovative projects in Colleges and universities in Guangdong Province (2015KTSCX156), the Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions (YQ2015168) and JSPS KAKENHI (15K05445).

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Authors and Affiliations

  1. College of Life Science, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Fenglan Liang

  2. School of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, 526061, People’s Republic of China

    Kuan Lu, Jingjing Yan, Weijie Lin, Wanqiu Ding, Husheng Lu, Dongting Lin, Deyun Ma & Liang Qin

  3. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata, 990-8560, Japan

    Hiroshi Sakiyama

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  1. Fenglan Liang
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Correspondence to Deyun Ma or Liang Qin.

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Liang, F., Lu, K., Yan, J. et al. Hydrostable coordination polymers of a methyl-functionalized 4,4′-bipyridine ligand: structure, stability, magnetic and luminescent properties. Transit Met Chem 41, 489–498 (2016). https://doi.org/10.1007/s11243-016-0044-5

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