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Supramolecular assembly of three Ag(I) coordination polymers derived from flexible N-containing ligands and polycarboxylates: synthesis, structures, and catalytic properties

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Abstract

Three Ag(I) coordination polymers [Ag(L1)]·(H3bptc)·H2O (1), [Ag2(L2)(oba)]·H2O (2), and [Ag2(L2)2]·(H2bptc) (3) [L1 = 1,4-bis(3,5-dimethylpyrazole)butane, L2 = 1,4-bis(2-methylbenzimidazole)butane, H4bptc = 3,3′,4,4′-biphenyltetracarboxylic acid, H2oba = 4,4′-oxybis(benzoic acid)] constructed from N-containing ligands with different flexibilities and organic carboxylates as co-ligands have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis. All three complexes display 1D chain structures, which are further extended into 2D supramolecular networks via non-classical C–H···O hydrogen bonding interactions. The fluorescence and catalytic properties of the complexes 1–3 have been investigated in detail. Complexes 2 and 3 reveal promising catalytic activities for the degradation of methyl orange in a Fenton-like process.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299), and the Graduate Student Innovation Fund of North China University of Science and Technology (2015S13).

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Authors and Affiliations

  1. College of Chemical Engineering, North China University of Science and Technology, Tangshan, 063009, Hebei, China

    Xu Zhang, Li Wei Liu, Zeng Chuan Hao & Guang Hua Cui

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  1. Xu Zhang
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  2. Li Wei Liu
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  3. Zeng Chuan Hao
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  4. Guang Hua Cui
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Corresponding author

Correspondence to Guang Hua Cui.

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Zhang, X., Liu, L.W., Hao, Z.C. et al. Supramolecular assembly of three Ag(I) coordination polymers derived from flexible N-containing ligands and polycarboxylates: synthesis, structures, and catalytic properties. Transition Met Chem 41, 459–466 (2016). https://doi.org/10.1007/s11243-016-0041-8

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  • DOI: https://doi.org/10.1007/s11243-016-0041-8

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